The removal of toxic metals from liquid effluents by ion exchange resins. Part XIII: Zinc(II)/H+/Lewatit OC-1026
DOI:
https://doi.org/10.3989/revmetalm.172Keywords:
Lewatit OC-1026, Liquid effluents, Multiwalled carbon nanotubes, Removal, Zinc(II)Abstract
Zinc(II) was removed, from aqueous solutions, by the ion exchange resin Lewatit OC-1026 (having di-2-ethylhexyl phosphoric acid as adsorbed functional group). Different experimental variables influencing metal uptake, such as, stirring speed (400–1200 min−1), temperature (20–60 °C), pH of the aqueous solution (1–4) and resin dosage (0.05–1 g·L−1) were investigated. The concentration of zinc(II) loaded onto the resin decreased with the increase of the temperature (exothermic reaction) in a spontaneous process, whereas equi-librium was achieved at shorter times as the temperature was increased. The experimental values fitted to the second order kinetic model (60 °C) or the pseudo-second order kinetic model (20 °C).The ion exchange process was pH-dependent, decreasing the percentage of zinc(II) loading onto the resin from pH 4 to pH 1. At pH 4, the rate law was best fitted to the particle diffusion model, and to the Langmuir type-2 isotherm. Zinc(II) removal from the aqueous solution using this resin is by far better than when oxidized or non-oxidized multiwalled carbon nanotubes were used as adsorbents for zinc(II). This element can be eluted from zinc-loaded resin using acidic solutions.
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Abdelrahman, E.A., Tolan, D.A., Nassar, M.Y. (2019). A tunable template-assisted hydrothermal synthesis of hydroxysodalite zeolite nanoparticles using various aliphatic organic acids for the removal of zinc(II) ions from aqueous media. J. Inorg. Organomet. Polym. Mater. 29, 229-247. https://doi.org/10.1007/s10904-018-0982-9
Abd El Salam, H.M., Zaki, T. (2019). A novel microwave synthesis of manganese based MOF for adsorptive of Cd(II), Pb(II) and Hg(II) ions from aqua medium. Egyptian J. Chem. 62, 1237-1251. https://doi.org/10.21608/ejchem.2019.6524.1550
Ahmad, S.Z.N., Wan Salleh, W.N., Ismail, A.F., Yusof, N., Mohd Yusop, M.Z., Aziz, F. (2020). Adsorptive removal of heavy metal ions using graphene-based nanomaterials: Toxicity, roles of functional groups and mechanisms. Chemosphere 248, 126008. https://doi.org/10.1016/j.chemosphere.2020.126008 PMid:32006836
Alguacil, F.J., Coedo, A.G., Dorado, T., Padilla, I. (2002). The removal of toxic metals from liquid effluents by ion exchange resins. Part I: chromium(VI)/sulphate/Dowex 1×8. Rev. Metal. 38 (4), 306-311. https://doi.org/10.3989/revmetalm.2002.v38.i4.412
Alguacil, F.J. (2002). The removal of toxic metals from liquid effluents by ion exchange resins. Part II: cadmium(II)/sulphate/Lewatit TP260. Rev. Metal. 38 (5), 348-352. https://doi.org/10.3989/revmetalm.2002.v38.i5.418
Alguacil, F.J. (2003). The removal of toxic metals from liquid effluents by ion exchange resins. Part III: copper(II)/sulphate/Amberlite 200. Rev. Metal. 39 (3), 205-209. https://doi.org/10.3989/revmetalm.2003.v39.i3.330
Alguacil, F.J. (2017a). The removal of toxic metals from liquid effluents by ion exchange resins. Part IV: chromium(III)/H+/Lewatit SP112. Rev. Metal. 53 (2), e093.
Alguacil, F.J. (2017b). The removal of toxic metals from liquid effluents by ion exchange resins. Part V: nickel(II)/H+/Dowex C400. Rev. Metal. 53 (4), e105.
Alguacil, F.J., Garcia-Diaz, I., Lopez, F., Rodriguez, O. (2017). Removal of Cr(VI) and Au(III) from aqueous streams by the use of carbon nanoadsorption technology. Desal. Water Treat. 63, 351-356. https://doi.org/10.5004/dwt.2017.0264
Alguacil, F.J. (2018a). The removal of toxic metals from liquid effluents by ion exchange resins. Part VI: manganese(II)/H+/Lewatit K2621. Rev. Metal. 54 (2), e116.
Alguacil, F.J. (2018b). The removal of toxic metals from liquid effluents by ion exchange resins. Part VII: manganese(VII)/H+/Amberlite 958. Rev. Metal. 54 (3), e125.
Alguacil, F.J., Escudero, E. (2018). The removal of toxic metals from liquid effluents by ion exchange resins. Part VIII: arsenic(III)/OH−/Dowex 1×8. Rev. Metal. 54 (4), e132.
Alguacil, F.J. (2019a). The removal of toxic metals from liquid effluents by ion exchange resins. Part IX: lead(II)/H+/Amberlite IR120. Rev. Metal. 55 (1), e138.
Alguacil, F.J. (2019b). The removal of toxic metals from liquid effluents by ion exchange resins. Part X: antimony(III)/H+/Ionac SR7. Rev. Metal. 55 (3), e152.
Alguacil, F.J. (2019c). The removal of toxic metals from liquid effluents by ion exchange resins. Part XI: cobalt(II)/H+/Lewatit TP260. Rev. Metal. 55 (4), e154.
Alguacil, F.J., Escudero, E. (2020). The removal of toxic metals from liquid effluents by ion exchange resins. Part XII: mercury(II)/H+/Lewatit SP112. Rev. Metal. 56 (1), e160.
Alguacil, F.J., López, F.A., Rodriguez, O., Martinez-Ramirez, S., Garcia-Diaz, I. (2016). Sorption of indium (III) onto carbon nanotubes. Ecotox. Environ. Safe. 130, 81-86. https://doi.org/10.1016/j.ecoenv.2016.04.008 PMid:27085001
Aliyu, A. (2019). Synthesis, electron microscopy properties and adsorption studies of Zinc (II) ions (Zn2+) onto as-prepared Carbon Nanotubes (CNTs) using Box-Behnken Design (BBD). Sci. African 3, e00069. https://doi.org/10.1016/j.sciaf.2019.e00069
Chasapis, C.T., Loutsidou, A.C., Spiliopoulou, C.A., Stefanidou, M.E. (2012). Zinc and human health: an update. Arch. Toxicol. 86, 521-534. https://doi.org/10.1007/s00204-011-0775-1 PMid:22071549
Chen, Y., Zhao, H., Li, Y., Zhao, W., Yang, X., Meng, X., Wang, H. (2019). Two-step preparation of an amidoxime-functionalized chelating resin for removal of heavy metal ions from aqueous solution. J. Chem. Eng. Data 64, 4037-4045. https://doi.org/10.1021/acs.jced.9b00402
Gümüş, D. (2019). Biosorptive application of defatted Laurus nobilis leaves as a waste material for treatment of water contaminated with heavy metal. Int. J. Phytoremediat. 21 (6), 556-563. https://doi.org/10.1080/15226514.2018.1537254 PMid:30729808
Ho, Y.-S. (2006). Review of second-order models for adsorption systems. J. Hazard. Mater. 136 (3), 681-689. https://doi.org/10.1016/j.jhazmat.2005.12.043 PMid:16460877
López Díaz-Pavón, A., Cerpa, A., Alguacil, F.J. (2014). Processing of indium(III) solutions via ion exchange with Lewatit K-2621 resin. Rev. Metal. 50 (2), e010. https://doi.org/10.3989/revmetalm.010
Maret, W. (2013). Zinc and human disease. In: Interrelations between Essential Metal Ions and Human Diseases. Sigel A., Sigel, H., Sigel, R. (Eds), Met. Ions Life Sci. Vol 13. Springer, Dordrecht, pp. 389-414. https://doi.org/10.1007/978-94-007-7500-8_12 PMid:24470098
Mirjavadi, E.S., Tehrani, R.M.A., Khadir, A. (2019). Effective adsorption of zinc on magnetic nanocomposite of Fe3O4/zeolite/cellulose nanofibers: kinetic, equilibrium, and thermodynamic study. Environ. Sci. Pollut. Res. 26, 33478-33493. https://doi.org/10.1007/s11356-019-06165-z PMid:31529345
Sakalova, H., Malovanyy, M., Vasylinycz, T., Palamarchuk, O., Semchuk, J. (2019). Cleaning of Effluents from Ions of Heavy Metals as Display of Environmentally Responsible Activity of Modern Businessman J. Ecol. Eng. 20 (4), 167-176. https://doi.org/10.12911/22998993/102841
Walker Jr., L. (2020). Clean Water Act (CWA) Alternate Test Procedures (ATP) (personal communication to F.J.A. 19/02/2020). U.S. Environmental Protection Agency (EPA). https://www.epa.gov/cwa-methods/alternate-test-procedures.
WHO (2020). Zinc in drinking-water. World Health Organization (accessed February 2020). https://www.who.int/water_sanitation_health/dwq/chemicals/zinc.pdf.
Wieszczycka, K., Filipowiak, K., Aksamitowski, P., Wojciechowska, I. (2020). Task-specific ionic liquid impregnated resin for zinc(II) recovery from chloride solutions. J. Molec. Liq. 299, 112115. https://doi.org/10.1016/j.molliq.2019.112115
Zand, A.D., Abyaneh, M.R. (2019). Equilibrium and kinetic studies in remediation of heavy metals in landfill leachate using wood-derived biochar. Desalin. Water Treat. 141, 279-300. https://doi.org/10.5004/dwt.2019.23571
Zhang, Q., Hou, Q., Huang, G., Fan, Q. (2020). Removal of heavy metals in aquatic environment by graphene oxide composites: a review. Environ. Sci. Pollut. Res. 27, 190-209. https://doi.org/10.1007/s11356-019-06683-w PMid:31838692
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