The removal of toxic metals from liquid effluents by ion exchange resins. Part XI: Cobalt(II) /H+/Lewatit TP260
DOI:
https://doi.org/10.3989/revmetalm.154Keywords:
Cobalt(II), Lewatit TP260, Liquid effluents, Multiwalled carbon nanotubes, RemovalAbstract
The removal of cobalt(II) from aqueous solutions by ion exchange with Lewatit TP260 resin was investigated. The experimental variables investigated in the present work were: stirring speed (300-1400 min-1), temperature (20-60 ºC), pH of the aqueous solution (1-5), resin dosage (0.07-0.5 g·L-1) and the aqueous ionic strength. Cobalt(II) was loaded onto the resin by a cation exchange reaction in an endothermic and spontaneous process. Metal uptake was defined by the aqueous diffusion rate law and the pseudo-first order kinetic model (20 ºC) and the pseudo-second order kinetic model (60 ºC), whereas the experimental results responded well to the Langmuir isotherm. Several resins as well as non-oxidized and oxidized multiwalled carbon nanotubes were tested in order to compare the uptake results with that of Lewatit TP260, whereas the selectivity of the Co(II)-Lewatit TP 260 system was compared against the presence of other cations (Co-metal binary solutions) in the aqueous phase. Cobalt(II) can be recovered from metal-loaded resin by the use of acidic solutions (HCl or H2SO4).
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