Electrical properties of ternary Bi-Ge-Sb and Al-Cu-Sb alloys





Electrical conductivity, Hardness, Materials testing, Microstructure


Electrical properties of ternary Bi-Ge-Sb and Al-Cu-Sb alloys. This paper presents review of electrical properties of two ternary systems based on Sb, ternary Bi-Ge-Sb and Al-Cu-Sb system. Beside electrical properties in paper are presented microstructures of both systems observed with light optical microscopy. On four samples microstructural analysis was carried out by scanning electron microscopy combined with energy dispersive spectrometry and X-ray powder diffraction technique. Moreover, micro hardness of selected alloys from the ternary Bi-Ge-Sb system was determined using Vickers hardness tests.


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Barrett, C.S., Cucka, P., Haefner, K. (1963). The crystal structure of antimony at 4.2, 78 and 298° K. Acta Crystallogr. 16, 451-453. https://doi.org/10.1107/S0365110X63001262

Bech, J., Corrales, I., Tume, P., Barceló, J., Duran, P., Roca, N., Poschenrieder, C. (2012). Accumulation of antimony and other potentially toxic elements in plants around a former antimony mine located in the Ribes Valley (Eastern Pyrenees). J. Geochem. Explor. 113, 100-105. https://doi.org/10.1016/j.gexplo.2011.06.006

Box, G., Draper, N. (2006). Response Surfaces, Mixtures, and Ridge Analyses. 2nd Ed., John Wiley and Sons, Inc., New Jersey.

Cornell, J.A. (1990). Experiments with Mixtures. Designs, Models, and the Analysis of Mixtures Data. 2nd Ed., John Wiley and Sons, Inc., New York. PMCid:PMC54465

Cucka, P., Barrett, C.S. (1962). The crystal structure of Bi and of solid solutions of Pb, Sn, Sb and Te in Bi. Acta Crystallogr. 15, 865-872. https://doi.org/10.1107/S0365110X62002297

Cui, X.D., Wang, Y.J., Hockmann, K., Zhou, D.M. (2015). Effect of iron plaque on antimony uptake by rice (Oryza sativa L.). Environ. Pollut. 204, 133-140. https://doi.org/10.1016/j.envpol.2015.04.019 PMid:25947970

Gierlotka, W. (2014). A new thermodynamic description of the binary Sb-Zn system. J. Min. Metall. Sect. B-Metall. B 50 (2), 149-155. https://doi.org/10.2298/JMMB131103020G

Guo, C., Li, C., Du, Z. (2016). Thermodynamic modeling of the Ga–Pt–Sb system. Calphad 52, 169-179. https://doi.org/10.1016/j.calphad.2016.01.001

Gray, T., Mann, N., Whitby, M. (2013). Electrical Conductivity of the elements. Available at http://periodictable.com/Properties/A/ElectricalConductivity.an.html (accesses 24.01.2016).

He, M., Wang, X., Wu, F., Fu, Z. (2012). Antimony pollution in China. Sci. Total Environ. 421-422, 41-50. https://doi.org/10.1016/j.scitotenv.2011.06.009 PMid:21741676

Illescas, S., Fernández, J., Asensio, J., Sánchez-Soto, M., Guilemany, J.M. (2009). Study of the mechanical properties of low carbon content HSLA steels. Rev. Metal. 45 (6), 424-431. https://doi.org/10.3989/revmetalm.0902

Johnson, C.A., Moench, H., Wersin, P., Kugler, P., Wenger, C. (2005). Solubility of antimony and other elements in samples taken from shooting ranges. J. Environ. Qual. 34 (1), 248-254. PMid:15647555

Kolarevic, M. (2004). Rapid product development. Ed. Foundation Andrejevic, Belgrad. PMid:15109152

Lazic, ?. (2004). Design of Experiments in Chemical Engineering: Practical Guide. Ed. Wiley-VCH Verlag GmbH & Co.KGaA, Weiheim, Alemania.

Liu, Y., Xu, J., Kang, Z., Wang, J. (2013). Thermodynamic descriptions and phase diagrams for Sb–Na and Sb–K binary systems. Thermochim. Acta 569, 119-126. https://doi.org/10.1016/j.tca.2013.07.009

Macgregor, K., MacKinnon, G., Farmer, J., Graham, M. (2015). Mobility of antimony, arsenic and lead at a former antimony mine, Glendinning, Scotland. Sci. Total Environ. 529, 213-222. https://doi.org/10.1016/j.scitotenv.2015.04.039 PMid:26011617

Mini?, D., Premovi?, M., Cosovi?, V., Manasijevi?, D., ?ivkovi?, D., Kostov, A., Talijan, N., (2013). Experimental investigation and thermodynamic calculations of the Al–Cu–Sb phase diagram. J. Alloy Compd. 555, 347-356. https://doi.org/10.1016/j.jallcom.2012.12.059

Myers, R.H., Montgomery, D.C., Anderson-Cook, C.M. (2009). Response Surface Methodology: Process and Product Optimization Using Designed Experiments. 3rd Ed., John Wiley and Sons, New Jersey, p. 704.

Pearson, W.B. (1985). The Cu2Sb and related structures. Z. Kristallogr. 171, 23-39.

Pierart, A., Shahid, M., Séjalon-Delmas, N., Dumat, C. (2015). Antimony bioavailability: Knowledge and research perspectives for sustainable agricultures. J. Hazard. Mater. 289, 219-234. https://doi.org/10.1016/j.jhazmat.2015.02.011 PMid:25726907

Premovic, M., Mini?, D., Cosovi?, V., Manasijevi?, D., ?ivkovi?, D. (2014). Experimental investigation and thermodynamic calculations of the Bi-Ge-Sb phase diagram. Metall. Mater. Trans. A 45(11), 4829-4841. https://doi.org/10.1007/s11661-014-2445-4

Serrano, N., Díaz-Cruz, J.M., Ari-o, C., Esteban, M. (2016). Antimony- based electrodes for analytical determinations. Trends Analyt. Chem. 77, 203-213. https://doi.org/10.1016/j.trac.2016.01.011

Sun, W., Xiao, E., Dong, Y., Tang, S., Krumins, V., Ning, Z., Sun, M., Zhao, Y., Wu, S., Xiao, T., (2016). Profiling microbial community in a watershed heavily contaminated by an active antimony (Sb) mine in Southwest China. Sci. Total Environ. 550, 297-308. https://doi.org/10.1016/j.scitotenv.2016.01.090 PMid:26820933

Swanson, H.E., Tatge, E. (1953). Standard X-ray diffraction powder patterns. Vol. 1, National Bureau of Standards, USA, pp. 1-95.

Verbeken, K., Infante-Danzo, I., Barros-Lorenzo, J., Schneider, J., Houbaert, Y. (2010). Innovative processing for improved electrical steel properties. Rev. Metal. 46(5), 458-468. https://doi.org/10.3989/revmetalm.1010

Vinhal, J., Gonçalves, A., Cruz, G., Cassella, R. (2016). Speciation of inorganic antimony (III & V) employing polyurethane foam loaded with bromopyrogallol red. Talanta 150, 539-545. https://doi.org/10.1016/j.talanta.2015.12.080 PMid:26838441

Westman, S. (1965). Refinement of the gamma - Cu9Al4 structure. Acta Chem. Scand. 19, 1411-1419. https://doi.org/10.3891/acta.chem.scand.19-1411

Woolley, J.C., Smith, B.A. (1958). Solid solution in A(III) B(V)compounds. Proc. Phys. Soc. 72(2), 214-223. https://doi.org/10.1088/0370-1328/72/2/306

Zobac, O., Sopou?ek, J., Kroupa, A. (2015). Calphad-type assessment of the Sb–Sn–Zn ternary system. Calphad 51, 51-56. https://doi.org/10.1016/j.calphad.2015.08.002



How to Cite

Premovic, M., Minić, D., Kolarevic, M., Manasijevic, D., Živković, D., Djordjevic, A., & Milisavljevic, D. (2017). Electrical properties of ternary Bi-Ge-Sb and Al-Cu-Sb alloys. Revista De Metalurgia, 53(3), e098. https://doi.org/10.3989/revmetalm.098




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