Análisis químico de cianuro en el proceso de cianuración: revisión de los principales métodos

F. Nava-Alonso; E. Elorza-Rodríguez; R. Pérez-Garibay; A. Uribe-Salas

doi:10.3989/revmetalm.2007.v43.i1.48

Chemical analysis of cyanide in cyanidation process: Review of methods

Authors

F. Nava-Alonso Centro de Investigación y de Estudios Avanzados del IPN
E. Elorza-Rodríguez Centro de Investigación y de Estudios Avanzados del IPN
R. Pérez-Garibay Centro de Investigación y de Estudios Avanzados del IPN
A. Uribe-Salas Centro de Investigación y de Estudios Avanzados del IPN

DOI:

https://doi.org/10.3989/revmetalm.2007.v43.i1.48

Keywords:

Cyanide chemical analysis, Cyanidation, Cyanide

Abstract

In cyanidation, the world wide method for precious metals recovery, the chemical analysis of cyanide, is a very important, but complex operation. Cyanide can be present forming different species, each of them with different stability, toxicity, analysis method and elimination technique. For cyanide analysis, there exists a wide selection of analytical methods, but most of them present difficulties because of the interference of species present in the solution. This paper presents the different available methods for chemical analysis of cyanide: titration, specific electrode and distillation, giving special emphasis on the interferences problem, with the aim of helping in the interpretation of the results.

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References

[1] P. Navarro, C. Vargas, R. Alvarez y F.J. Alguacil, Rev. Metal. Madrid 41 (2005) 12-20.

[2] A. Smith y T. Mudder, Chemistry and Treatment of Cyanidation Wastes, Mining Journal Books Limited, London, 1991.

[3] P. Navarro, C. Vargas, F.J. Alguacil y R. Alvarez, Rev. Metal. Madrid Vol. Extr. (2005) 69-73.

[4] J.J. yáñez-Traslaviña, M.A. Vargas-Avila, I.H. García-Páez y J.E. Pedraza-Rosas, Rev. Metal. Madrid 41 (2005) 116-125.

[5] L. Chacón, F. Ruiz y R. Zapico, Rev.Metal. Madrid. Vol. Extr. (2005) 390-394.

[6] J. Lu, D.B. Dreisinger y W.C. Cooper, Hydrometallurgy 66 (2002) 23-36. doi:10.1016/S0304-386X(02)00081-6

[7] K.L. Rees y J.S.J. Van-Deventer, Miner. Eng. 12 (1999) 877-892. doi:10.1016/S0892-6875(99)00075-8

[8] R. Shantz y J. Reich, Hydrometallurgy 3 (1978) 99-109. doi:10.1016/0304-386X(78)90014-2

[9] N. Hedley y D.M. Kentro, Trans.Can. Inst. Min.Metall. XLVIII (1945) 237-251.

[10] ASTM, Standard Practices for Preparation of Sample Containers and for Preservation of Organic Constituents, 1995.

[11] L.S. Clesceri, A.E. Greenberg y R.R. Trussell, Standard Methods for the Examination of Water and Wastewater, 17th ed., 1989.

[12] R. Berman, D. Christmann y C. Renn, American Environmental Laboratory (1993)

[13] D. Ingersoll, W.R. Harris y D.C. Bomberger, Anal. Chem. 53 (1981) 2.254-2.258.

[14] ASTM, Standard Test Methods for Cyanides in Water D-2036-91, 1991.

[15] J.H. Riseman, American Laboratory (1972) 63- 67.

[16] L. Bark y H. Higson, Analyst (1963) 751-760. doi:10.1039/an9638800751

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Published

2007-02-28

How to Cite

Nava-Alonso, F., Elorza-Rodríguez, E., Pérez-Garibay, R., & Uribe-Salas, A. (2007). Chemical analysis of cyanide in cyanidation process: Review of methods. Revista De Metalurgia, 43(1), 20–28. https://doi.org/10.3989/revmetalm.2007.v43.i1.48

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Issue

Vol. 43 No. 1 (2007)

Section

Reviews

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