Sustainable Metallographic Preparation: Specific Case of Nickel Aluminium Bronze (NAB), Manganese Aluminium Bronze (MAB) and a Duplex Brass

Authors

DOI:

https://doi.org/10.3989/revmetalm.e271.1651

Keywords:

Brass, Bronze, Etching, Metallography, Microstructure, Polishing

Abstract


Nickel Aluminium Bronze (NAB) and Manganese Aluminium Bronze (MAB) are highly alloyed metallic systems that are widely used in naval applications due to their excellent corrosion resistance and mechanical and tribological properties, such as cavitation and erosion resistance. Duplex brass is also an excellent option due to its ability to increase mechanical properties and corrosion resistance by selected thermal treatments. Chemical reagents currently used for metallography in research laboratories and in industry, are based mainly upon acidic iron chloride solutions. This work shows the results of microstructural features of these alloys after grinding and polishing of selected specimens in as cast state, with alumina or diamond paste of different sizes, using tap water and distilled water. The main conclusion is that the microstructure of these materials is perfectly revealed without the usual etching step involving a chemical reagent, thus reducing both the environmental and the economic impact.

Downloads

Download data is not yet available.

References

Abdel-Karim, A.M., El-Shamy, A.M. (2022). A review on green corrosion inhibitors for protection of archaeological metal artifacts. J. Bio. Tribo. Corros. 8, 35. https://doi.org/10.1007/s40735-022-00636-6

Al-Hashem A., Riad, W. (2002). The role of microstructure of nickel-aluminium-bronze alloy on its cavitation corrosion behavior in natural seawater. Mater. Charact. 48 (1), 37-41. https://doi.org/10.1016/S1044-5803(02)00196-1

Basumatary, J., Wood, R.J.K. (2017). Synergistic effects of cavitation erosion and corrosion for nickel aluminium bronze with oxide film in 3.5% NaCl solution. Wear 376-377 (Part B), 1286-1297. https://doi.org/10.1016/j.wear.2017.01.047

Berlanga-Labari, C., Claver, A., Biezma-Moraleda, M.V., Palacio, J.F. (2023). Study of Effect of Nickel Content on Tribocorrosion Behaviour of Nickel-Aluminium-Bronzes (NABs). Lubricants 11 (2), 43. https://doi.org/10.3390/lubricants11020043

Biezma, M.V., Gómez de la Rasilla, O., Haubner, R., Linhardt, P. (2022). Etching of Manganese Aluminum Bronze by Ultrasound in Seawater. Prakt. Metallogr. 59 (5), 236-250. https://doi.org/10.1515/pm-2022-0027

Biezma, M.V., Strobl, S., Linhardt, P., Ball, G., Haubner, R. (2023). Dezincification in cast and heat-treated alpha-beta brass samples. Prakt. Metallogr. 60 (10). https://doi.org/10.1515/pm-2023-1053

Böhm, J., Haubner, R., Linhardt, P., Biezma Moraleda, M.V. (2019). Corrosion behaviour of a heat treated manganese-nickel-aluminium bronze (MAB) in simulated fresh and sea water. 25 EUROCORR 2019, Sevilla, Spain. http://hdl.handle.net/20.500.12708/101178.

Cobo, I., Biezma-Moraleda, M.V., Linhardt, P. (2022). Corrosion evaluation of welded nickel aluminum bronze and manganese aluminum bronze in synthetic sea water. Mater. Corros. 73 (11), 1788-1799. https://doi.org/10.1002/maco.202213328

Cobo Ocejo, I., Biezma Moraleda, M.V., Linhardt, P. (2022). Corrosion Behavior of Heat-Treated Nickel-Aluminum Bronze and Manganese-Aluminum Bronze in Natural Waters. Metals 12 (3), 380. https://doi.org/10.3390/met12030380

Dinaharan, I., Akinlabi, E.T. (2017). Application of Color Metallography to Study the Microstructure of Friction Stir-Welded Dual-Phase Brass Using Various Etchants. Metallogr. Microstruct. Anal. 6, 99-105. https://doi.org/10.1007/s13632-017-0337-x

Farabi, E., Zarei-Hanzaki, A., Pishbin, M.H., Moallemi, M. (2015). Rationalization of duplex brass hot deformation behavior: The role of microstructural components. Mater. Sci. Eng. A 641, 360-368. https://doi.org/10.1016/j.msea.2015.06.042

Gorovei, M.C., Benea, L. (2018). The effect of some key changes in the chemistry of water in relation to copper and brass corrosion control. IOP Conf. Ser.: Mater. Sci. Eng. 374 (1), 012057. https://doi.org/10.1088/1757-899X/374/1/012057

Gregg, N.R. (1990). A Microstructural Investigation of a Duplex Chill Cast Brass Grain Refined with Aluminium and Boron. Doctoral dissertation, University of Surrey, UK.

Han, Z., Huang, X., Chen, J., Chen, J., Zhou, H. (2024). Study on the compounding of cysteine modified Schiff base and decanoic acid as corrosion inhibitors for bronze with patina. Surf. Interfaces 46, 103996. https://doi.org/10.1016/j.surfin.2024.103996

Khalili, M., Eivani, A.R., Seyedein, S.H., Jafarian, H.R. (2022). The effect of multi-pass friction stir processing on microstructure and mechanical properties of dual-phase brass alloy. J. Mater. Res. Technol. 21, 1177-1195. https://doi.org/10.1016/j.jmrt.2022.09.069

Lazar, I., Bordeasu, I., Popoviciu, M.O., Mitelea, I., Craciunescu, C.M., Pirvulescu, L.D., Sava, M., Micu, L.M. (2019). Evaluation of the brass CuZn39Pb3 resistance at vibratory cavitation erosion. IOP Conf. Ser.: Mater. Sci. Eng. 477 (1), 012002. https://doi.org/10.1088/1757-899X/477/1/012002

Lazar, I., Bordeasu, I., Pirvulescu, L.D., Hluscu, M., Mitelea, I., Ghera, C. (2021). The behavior to cavitation erosion-corrosion of the CuZn39Pb3 brass structures, obtained by in-depth heat treatments. J. Phys.: Conf. Ser. 1781 (1), 012004. https://doi.org/10.1088/1742-6596/1781/1/012004

Linhardt, P., Strobl, S., Böhm, J., Biezma, M.V., Haubner, R. (2021). Heat Treatment Effect on the Microstructure and the Corrosion Resistance of Manganese-Aluminum Bronzes. Prakt. Metall. 58 (2), 72-82. https://doi.org/10.1515/pm-2020-0004

Linhardt, P., Biezma, M.V., Strobl, S., Haubner, R. (2023). Influence of Cavitation in Seawater on the Etching Attack of Manganese-Aluminum-Bronzes. Solid State Phenom. 341 (8), 25-30. https://doi.org/10.4028/p-7nbo00

Markusi, M., Otmačić Ćurković, H., Hajdari, Z., Kristan, E. (2015). Patinated bronze protection by long chain organic acids. In EUROCORR 2015 (European Corrosion Congress). p. 1582

Mora Pozo, E., Venegas Ledo, E. (2011). Caracterización del Latón. Rev. Met. UTO 30, 57-64.

Moriarty, M., Wu, Y., Murray, T., Hutchinson, C. (2021). The effect of phase fraction, size and shape on the dezincification of duplex brasses. Corros. Sci. 184, 109366. https://doi.org/10.1016/j.corsci.2021.109366

Mota, N.M., Tavares, S.S.M., do Nascimento, A.M., Zeeman, G., Biezma Moraleda, M.V. (2021). Failure analysis of a butterfly valve made with nickel aluminum Bronze (NAB) and manganese aluminum Bronze (MAB). Eng. Fail. Anal. 129, 105732. https://doi.org/10.1016/j.engfailanal.2021.105732. https://doi.org/10.1016/j.engfailanal.2021.105732

Ni, D.R., Xiao, B.L., Ma, Z.Y., Qiao, Y.X., Zheng, Y.G. (2010). Corrosion properties of friction-stir processed cast NiAl bronce. Corros. Sci. 52 (5), 1610-1617. https://doi.org/10.1016/j.corsci.2010.02.026

Orzolek, S.M., Semple, J.K., Fisher, C.R. (2022). Influence of processing on the microstructure of nickel aluminum bronze (NAB). Addit. Manuf. 56, 102859. https://doi.org/10.1016/j.addma.2022.102859

Procaccini, R., Schreiner, W.H., Vázquez, M., Ceré, S. (2013). Surface study of films formed on copper and brass at open circuit potential. Appl. Surf. Sci. 268, 171-178. https://doi.org/10.1016/j.apsusc.2012.12.050

Qin, Z., Li, X., Xia, D., Zhang, Y., Feng, C., Wu, Z., Hu, W. (2022). Effect of compressive stress on cavitation erosion-corrosion behavior of nickel-aluminum bronze alloy. Ultrason. Sonochem. 89, 106143. https://doi.org/10.1016/j.ultsonch.2022.106143 PMid:36058140 PMCid:PMC9460524

Richardson, I. (2016). Guide to Nickel Aluminum Bronze for Engineers. Copper Development Association, Publication Nº 222. https://copper.org/applications/marine/nickel_al_bronze. (Accessed Sep. 2025)

Rivero, P.J.; Berlanga, C.; Palacio, J.F.; Biezma-Moraleda, M.V. (2021). Effect of Ti on microstructure, mechanical properties and corrosion behavior of a nickel-aluminum bronze alloy. Mater. Res. 24 (2), e20200335. https://doi.org/10.1590/1980-5373-mr-2020-0335

Roy, S., Coyne, J.M.; Novak, J.A., Edwards, M.A. (2018). Flow-induced failure mechanisms of copper pipe in potable water systems. Corros. Rev. 36 (5), 449-481. https://doi.org/10.1515/corrrev-2017-0120

Song, Q.N., Xu, N., Bao, Y.F., Jian, Y.F., Gu, W., Zheng, Y., Qiao, Y.X. (2017). Corrosion and Cavitation Erosion Behaviors of Two Marine Propeller Materials in Clean and Sulfide-Polluted 3.5% NaCl Solutions. Acta Metall. Sin. 30 (8), 712-720. https://doi.org/10.1007/s40195-017-0602-7

Tian, Y., Zhao, H., Yang, R., Liu, X., Li, H., Chen, X. (2022). Effects of Bacillus sp. adhesion on cavitation erosion behaviour of nickel aluminium bronze in artificial seawater. Wear 498-499, 204344. https://doi.org/10.1016/j.wear.2022.204344

Voort, V. (2004). ASM Handbook, Metallography and Microstructures. Volume 9, ASM International, Materials Park, OH, USA, pp. 445-463.

Yao, C.L., Shim, D.S. (2022). Corrosive properties of CuNi2SiCr fabricated through directed energy deposition on a nickel-aluminum bronze substrate. J. Alloys Compd. 918, 165776. https://doi.org/10.1016/j.jallcom.2022.165776

Zhang, B.B., Wang, J.Z., Yan, F. (2018). Load-dependent tribocorrosion behaviour of nickel-aluminium bronze in artificial seawater. Corros. Sci. 131, 252-263. https://doi.org/10.1016/j.corsci.2017.11.028

Zhao, X., Qi, Y., Wang, J., Peng, T., Zhang, Z., Li, K. (2020). Effect of Weld and Surface Defects on the Corrosion Behavior of Nickel Aluminum Bronze in 3.5% NaCl Solution. Metals 10 (9), 1227. https://doi.org/10.3390/met10091227

Wu, Z., Cheng, Y.F., Liu, L., Weijie, L.V., Hu, W. (2015). Effect of heat treatment on microstructure evolution and erosion-corrosion behavior of a nickel-aluminum bronze alloy in chloride solution. Corros. Sci. 98, 260-270. https://doi.org/10.1016/j.corsci.2015.05.037

Published

2024-12-30

How to Cite

Biezma Moraleda, M. V., Merino Galván, L., Fernández Palacio, J. ., & Berlanga Labari, C. (2024). Sustainable Metallographic Preparation: Specific Case of Nickel Aluminium Bronze (NAB), Manganese Aluminium Bronze (MAB) and a Duplex Brass. Revista De Metalurgia, 60(4), e271. https://doi.org/10.3989/revmetalm.e271.1651

Issue

Section

Articles