Relationship between Microstructure, Corrosion, and Mechanical Degradation in P110 and N80 Drill Steels

Authors

DOI:

https://doi.org/10.3989/revmetalm.e291.1753

Keywords:

Carbon steel, Corrosion, Hardness, Mechanical properties, N80 steel grade, P110 steel grade

Abstract


This study provides a comprehensive examination of how corrosion impacts the structure-property relationships of P110 and N80 carbon steels, which are widely utilized for tubing and casing in the oil and gas industry. A multi-technique approach was employed, including optical microscopy, X-ray fluorescence, Vickers hardness testing, and confocal microscopy, to analyze samples in both their as-received and corroded states. The results reveal that corrosion significantly degrades the microstructure and mechanical properties of both steels. P110 steel, characterized by a tempered martensite microstructure and higher initial strength, exhibits severe localized pitting corrosion and a substantial increase in surface roughness. In contrast, N80 steel shows more uniform and diffuse degradation with significant surface oxide growth. Corrosion induces a notable reduction in hardness and a non-linear evolution of deformation under load, highlighting the complex interplay between microstructure and environmental degradation. The innovative contribution of this work lies in the development of a predictive framework that links these experimental observations to material service life. This framework provides a valuable tool for the oil and gas industry, enabling a shift from reactive maintenance to proactive asset management, thereby enhancing operational safety and economic efficiency.

Downloads

Download data is not yet available.

References

Abbas, S.H., Ridha, A.M., Rashid, K.H., Khadom, A.A. (2023). Biosorption of Congo red dye removal from aqueous solution using fennel seed spent and garlic peel. Int. J. Environ. Sci. Technol. 20, 13845–13858.

Abbott, M. (2019). Organizational structure, public policy, and technological change: The origins of the dominion steel industries. Manag. Organ. Hist. 14 (3), 245–265.

Aghapanah, H., Saeeidi Rad, A., Rasti, R. (2024). A survey of deep learning in advancing steel industry standards. 2024 20th CSI International Symposium on Artificial Intelligence and Signal Processing. IEEE, pp. 1–7.

Andersen, J.P., Hyman, B. (2001). Energy and material flow models for the US steel industry. Energy 26 (2), 137–159.

Ben Ghorbal, G., Tricoteaux, A., Thuault, A., Ageorges, H., Roudet, F., Chicot, D. (2020). Mechanical properties of thermally sprayed porous alumina coating by Vickers and Knoop indentation. Ceram. Int. 46 (12), 19843–19851.

Bjorhovde, R. (2010). Performance and design issues for high strength steel in structures. Adv. Struct. Eng. 13 (3), 403–411.

Birat, J.P. (2021). Case Study – Construction Material (Steel). In Life cycle assessment: A metric for the circular economy. Borrion. A., Black, M.J., Mwabonje, O. (Eds.), Life Cycle Assessment. The RSC, Cambridge, pp. 81–104.

Branagan, D.J. (2005). Enabling factors toward production of nanostructured steel on an industrial scale. J. Mater. Eng. Perform. 14, 5–9.

Cai, Y., Guo, P., Liu, D., Chen, S., Liu, J. (2010). Comparative study on CO2 corrosion behavior of N80, P110, X52 and 13Cr pipe lines in simulated stratum water. Sci. China Technol. Sci. 53, 2342–2349.

Geiger, G.H. (2000). Iron and steel, economic aspects. In: Kirk-Othmer Encyclopedia of Chemical Technology. Wiley, New York.

Geng, X., Wang, F., Wu, H.-H., Wang, S., Wu, G., Gao, J., Zhao, H., Zhang, C., Mao, X. (2023). Data-driven and artificial intelligence accelerated steel material research and intelligent manufacturing technology. MGE Advances 1 (1), e10.

Ghebrihiwet, N., Kinda, T. (2021). Downstream beneficiation: A cross-country analysis of factors underlying the emergence of a steel industry. Resour. Policy 70, 101975.

Guniputi, B.N., Murigendrappa, S.M. (2018). Influence of Gd on the microstructure, mechanical and shape memory properties of Cu-Al-Be polycrystalline shape memory alloy. Mater. Sci. Eng. A 737, 245–252.

Hameed, W.F., Rashid, K.H., Khadom, A.A. (2022). Optimization of inhibition performance of hexamethylenetetramine for corrosion of mild steel in CO₂-saturated brine produced water. AIP Conf. Proc. 2495, 020008.

Hassan, H.S., Rashid, K.H., Al-azawi, K.F., Khadom, A.A., Mahood, H.B. (2024). Synthesis and diagnosis of new heterocyclic compound as corrosion inhibitor for mild steel in acidic solution. Diyala J. Eng. Sci. 17 (4), 1–15.

Haweel, C.K., Zozan, J.L., Khadom, A.A., Rashid, K.H. (2025). Boiler corrosion in thermal power plant: kinetics and mathematical studies. Heat Transfer 54 (7), 4299-4307.

He, X., Zhang, M., Xu, T., Lei, L., Li, Y. (2023). Evaluation of mechanical properties of different casing drilling steels. Metals 13 (2), 427.

Hou, D., Xiao, Z., Zhang, Z., Deng, H., Lu, Q., Shi, T. (2022). Environmental assisted cracking and strength attenuation effect computing on the mechanical properties of casing steel P110 for industrial revolution 5.0 applications in sour well environments. Soft Comput. 26, 6777–6787.

Hussein, S.A., Khadom, A.A., Kadhum, A.A., Mahood, H.B., Rashid, K.H. (2024). Mass transfer influence on the corrosion inhibition of N80 steel in 1M H₂SO₄ by green corrosion inhibitor using MATLAB. Int. J. Electrochem. Sci. 19 (12), 100764.

Jian, M., Juntao, Y., Yan, H., Xiuqing, X., Lei, L., Ke, W. (2018). Corrosion behavior of P110 tubing steel in the CO2- saturated simulated oilfield formation water with element sulphur addition. Rare Metal Mat. Eng. 47 (7), 1965–1972.

Jiang, Y., Xu, S., Gao, S. (2022). The effect of initial alloy temper on corrosion resistance for Al-Zn-Mg-Cu alloy. Corros. Sci. 209, 110730.

Jing, J., Shan, H., Zhu, X., Luo, H., Sun, H., Song, W. (2023). The effect of string mechanical properties degradation on wellhead growth of offshore HPHT wells. Pet. Sci. Technol. 42 (19), 2608–2632.

Khalaf, A.H., Xiao, Y., Lin, B., Li, Z., Ning, X., Wu, B., Nie, Z., Tang, J. (2025). Corrosion resistance assessment of P110 SS and 2205 DSS materials in extreme Iraqi oil wellbore environments: A comparative study and microstructural analysis. Anti-Corros. Methods Mater. 72 (4), 560–582.

Li, S., Zhang, K., Wang, Q. (2019). Experimental study on the corrosion of a downhole string under flue gas injection conditions. Energy Sci. Eng. 7 (6), 2620–2632.

Lin, N., Xie, F., Zhou, J., Zhong, T., Wu, X., Tian, W. (2010). Microstructures and wear resistance of chromium coatings on P110 steel fabricated by pack cementation. J. Cent. South Univ. Technol. 17, 1155–1162.

Lin, N., Xie, F., Zou, J., Tang, B. (2013). Slurry erosion behaviors of P110 steel and chromizing coating in liquid-solid two-phase flow. Sci. China Technol. Sci. 56, 1415–1423.

Liu, J.X., Sun, S.B., Chen, F., Tong, Y.X., Guan, L. (2022). High temperature wear behavior of Ni-rich NiTi-based alloys. J. Mater. Res. Technol. 20, 440–447.

Lovgren, C.A. (1968). Forces of economic change—Steel U.S.A. JOM 20, 17–21.

Lv, D., Tian, L., Wang, L., Li, Y., Tu, W. (2024). Microstructure and wear resistance analysis of TiC/Ni composite coating on P110 steel by argon arc cladding. Trans. Indian Inst. Met. 77, 2173–2181.

Ma, L., Du, Y., Meng, Z., Ma, L., Liu, Z., Liu, P. (2020). Effect of process parameters on steel tube roundness in straightening process. J. Iron Steel Res. Int. 27, 1270–1283.

Manojlović, V., Raić, K.T., Tarlanović, M., Wang, L.H., Youngning, Z., Li, G. (2025). Statistics and sustainability in the iron and steel industry: from resources to low-carbon technologies. Metall Mater. Data 2 (4), 131–140.

Mansour, A.A., Al-hadeethi, M.R., Lgaz, H., Subbiah, K., Messali, M., Lee, H., Bazzi, L., Salghi, R. (2023). Exploring the potential of isonicotinohydrazide derivatives in N80 steel corrosion control: An integrated approach through synthesis, modeling, and experimentation in acidic environments. Colloid. Surf. A Physicochem. Eng. Asp. 679, 132542.

Mohammed, W.A., Rashid, K.H., Al-azawi, K.F., Khadom, A.A. (2025). Novel chalcone-derived bases as efficient corrosion inhibitor for carbon steel in 1M HCl: synthesis, diagnosis, gravimetrical, electrochemical, morphological, and computational insights. ChemistrySelect 10 (34), e03378.

Neyra Astudillo, M.R., Núñez, N.M., López Pumarega, M.I., Ferrari, G., Ruzzante, J., Gómez, M. (2022). Study of martensite induced by deformation with magnetic Barkhausen noise technique. J. Magn. Magn. Mater. 556, 169454.

Okafor, P.C., Liu, C.B., Zhu, Y.J., Zheng, Y.G. (2011). Corrosion and corrosion inhibition behavior of N80 and P110 carbon steels in CO2-saturated simulated formation water by rosin amide imidazoline. Ind. Eng. Chem. Res. 50 (12), 7273–7281.

Paxton, H. (2000). Steel. In: Kirk-Othmer Encyclopedia of Chemical Technology. Wiley, New York

Rashid, K.H., Khadom, A.A. (2018). Evaluation of environmentally friendly inhibitor for corrosion of mild steel in phosphoric acid solution: unconventional approach. Anti-Corros. Methods Mater. 65 (5), 506-514.

Rashid, K.H., Khadom, A.A. (2020). Mathematical modeling and electrochemical behavior for corrosion inhibition of steel by kiwi juice extract. J. Bio-Tribo-Corros. 6, 13.

Rashid, K.H., Khadom, A.A., Mahood, H.B., Campbell, A.N. (2020a). The effect of mass transfer on corrosion in oilfield production processes by wastewater enriched with CO₂: computer aided modeling and experimental verification. CSCEE. 2, 100030.

Rashid, K.H., Khadom, A.A., Mahood, H.B. (2020b). Aluminum ASA 6061 anodizing process by chromic acid using Box–Wilson central composite design: optimization and corrosion tendency. Met. Mater. Int. 27 (4), 4059–4073.

Rashid, K.H., Al-azawi, K.F., Jasim, Z.I., Khadom, A.A. (2024). Optimization for corrosion inhibition of steel in hydrochloric acid by DHOT as a novel corrosion inhibitor. Pet. Chem. 64, 996–1001.

Rashid, K.H., Khadom, A.A., Kadhum, A.A. (2025). Optimization of process parameters for 4643 Al alloy anodization in mixed oxalic/phosphoric electrolytes: Doehlert experimental design. Int. J. Electrochem. Sci. 20 (3), 100945.

Rzaij, D.R., Khadom, A.A., Rashid, K.H., Al-Amiery, A.A. (2025). Influence of chloride ions, temperature, and pressure on boiler tubes corrosion: experimental, mathematical, and kinetics perspective. React. Kinet. Mech. Catal. 138, 3705–3724.

Shareef Jasim, A., Khadom, A.A., Rashid, K.H., Al-azawi, K.F. (2022). (3,5-dimethyl-1H-pyrazol-1-yl) (4-((3,4-dimethoxybenzylidene)amino)phenyl)methanone as a novel corrosion inhibitor for low-carbon steel in hydrochloric acid: synthesis, diagnosis, and application. Results Chem. 4, 100569.

Singh, A., Lin, Y., Quraishi, M., Olasunkanmi, L., Fayemi, O., Sasikumar, Y., Ramaganthan, B., Bahadur, I., Obot, I., Adekunle, A., Kabanda, M., Ebenso, E. (2015). Porphyrins as corrosion inhibitors for N80 steel in 3.5% NaCl solution: Electrochemical, quantum chemical, QSAR and Monte Carlo simulations studies. Molecules 20 (8), 15122–15146.

Subekti, N., Arlan, A.S., Soedarsono, J.W., Rustandi, A. (2018). Corrosion inhibition by a Caesalpinia sappan L modified imidazoline for carbon steel API 5L grade X60 in HCl 1M environment. Mater. Sci. Forum 929, 158–170.

Xu, Z., Akiyama, M., Lim, S., Srivaranun, S., Frangopol, D.M., Miyazato, S., Li, A. (2024). Investigation of corrosion-induced cracks using corrosion products quantified by an X-ray technique and FE analysis of single- and multiple-rebar beams. Cement Concr. Compos. 151, 105565.

Yadav, M., Kumar, S., Tiwari, N., Bahadur, I., Ebenso, E.E. (2015). Experimental and quantum chemical studies of synthesized triazine derivatives as an efficient corrosion inhibitor for N80 steel in acidic medium. J. Mol. Liquids 212, 151–167.

Yan, W. (2004). Corrosion factors of P110 steel in simulated CO2/H2S environment. Oil Field Equip. 18–21

Zeng, D., Huang, Z., Yu, Z., Shi, S., Yi, Y., Liu, C., Tian, G., Sun, Y. (2021). Effects of CO2 gassy supercritical phase transition on corrosion behaviors of carbon steels in saturated vapor environment. J. Cent. South Univ. 28, 325–337.

Downloads

Published

2026-06-01

How to Cite

Dairi, O. ., Hamidouche, M., Ilyes Habia, M., Malou Hamidouche, Z. ., Bali, T., Liamine Bella, M. ., & Zegadi, A. . (2026). Relationship between Microstructure, Corrosion, and Mechanical Degradation in P110 and N80 Drill Steels. Revista De Metalurgia, 62(1), e291. https://doi.org/10.3989/revmetalm.e291.1753

Issue

Section

Articles