Analysis of the η phase of the Al-Cu-Zn system and its relationship with τ' and α phases
DOI:
https://doi.org/10.3989/revmetalm.e264.1681Keywords:
Aging, Homogenized, Al-Cu-Zn ternary alloys, PhasesAbstract
In this study, a characterization analysis of a series of Al-Cu-Zn alloys was carried out, focusing on the relationship between the η phase and the surrounding phases. As part of this analysis, the nanohardness of the η phase was measured, along with its average perimeter and the contact perimeter shared with the τ' and α phases—an aspect that has not been previously examined in this type of alloy. In order to accomplish this, the alloys were analyzed using a scanning electron microscope in backscattered electron mode to identify and distinguish each phase. The results demonstrate that a multiple linear regression model, using hardness as the dependent variable and the aforementioned morphological parameters as independent variables, yields a near-zero error. This finding indicates a strong correlation between these variables and both the hardness and the chemical composition of the alloy. The use of phase perimeter as a predictive parameter has not been previously applied to Al-Cu-Zn alloys. Therefore, this study provides a novel methodological contribution, offering a framework that may support the advancement of image analysis techniques in the characterization of multiphase metallic systems.
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References
Börnstein, L. (2005). Ternary Alloy System Phase Diagrams, Crystallographic and Thermodinamic Data. Editors: G. Effenberg, S. Ilyenko. Vol. 1, 11, Springer, New York, USA.
Ciach, R., Krol, J., Wegrzynt. K. (1969). Etudies on four phases transformation in AlZn-78 alloy containing 1-3 per cent of copper. Bulletin de L'Academie Polonaise des Sciences 17 (4), 371-378.
Dorantes-Rosales, H.J., López-Hirata, V.M., Zhu, Y.H. (1999). Decomposition process in a Zn-22wt.% Al-2wt.% Cu alloy. Mater. Sci. Eng. A 271 (1-2), 366-370. https://doi.org/10.1016/S0921-5093(99)00255-5
Effenberg, G. (2005). Selected Systems form Al-Cu-Fe to Al-Fe-Ti, Ternary Alloys Systems. Part 2. Springer, Berlin, pp. 329-358.
Flores-Ramos, A., Dorantes-Rosales, H.J., López-Hirata, V.M., Hernández-Santiago, F., González-Velázquez, J.L., Torres-Castillo, A.A., Rivas-López, D.I. (2014). Transformaciones de fase en aleaciones Zn-22% Al-2% Cu y Zn-22% Al-2% Cu-X (X= 1, 2 y 3% Ag) envejecidas isotérmicamente. Rev. Metal. 50 (4), e026. https://doi.org/10.3989/revmetalm.026
Ghiaasiaan, R., Amirkhiz, B.S., Shankar, S. (2017). Quantitative metallography of precipitating and secondary phases after strengthening treatment of net shaped casting of Al-Zn-Mg-Cu (7000) alloys. Mat. Sci. Eng. A 698, 206-217. https://doi.org/10.1016/j.msea.2017.05.047
Hall, E.O. (1951). The deformation and ageing of mild steel: III discussion of results. Proc. Phys. Soc. B 64 (9), 747. https://doi.org/10.1088/0370-1301/64/9/303
Houghton, M.E., Murray, M.T. (1983). An introduction to Zinc alloys. Met. Forum 6 (4), 211-225.
Hsu, C.C., Wang, W.H. (1996). Superplastic forming characteristics of a Cu-Zn-Al-Zr shape memory alloy. Mater. Sci. Eng. A 205 (1-2), 247-253. https://doi.org/10.1016/0921-5093(95)09884-4
Iwaoka, H., Hirosawa, S. (2020). First-principles calculation of elastic properties of Cu-Zn intermetallic compounds for improving the stiffness of aluminum alloys. Comput. Mater. Sci. 174, 109479. https://doi.org/10.1016/j.commatsci.2019.109479
Kang, G.C., Hong, S.H., Park, H.J., Lee, J.P., Lee, J.K., Wang, W.M., Kim, K.B. (2023). Influence of grain boundary modification on color transition behavior of cu-al-zn-sn alloys with low stacking fault energy. J. Alloys Compod. 960, 171033. https://doi.org/10.1016/j.jallcom.2023.171033
Kasama, R., Iwaoka, H., Umeda, Y., Yongpeng, T., Hirosawa, S., Watanabe, H., Fujita, M. (2020). Considerable improvement in elastic moduli and the underlying mechanism of Al-Cu-Zn alloy subjected to aging treatments. Materialia 14, 100911. https://doi.org/10.1016/j.mtla.2020.100911
Khan, M.A., Xu, C., Hamza, M., Afifi, M.A., Qaisrani, N.A., Sun, H., Wang, B., Khan, W.Q, Yasin, G., Liao, W.B. (2023). Enhanced tensile strength in an Al-Zn-Mg-Cu alloy via engineering the precipitates along the grain boundaries. J. Mater. Res. Technol. 22, 696-705. https://doi.org/10.1016/j.jmrt.2022.11.155
Kim, S.J., Kim, K.S., Kim, S.S., Kang, C.Y., Suganuma, K. (2008). Characteristics of Zn-Al-Cu alloys for high temperature solder application. Materials Transactions 49 (7), 1531-1536. https://doi.org/10.2320/matertrans.MF200809
Klopotov, A., Ivanov, Y., Vlasov, V., Dedov, N., Loskutov, O. (2016). Phase transformations in the system Cu-Zn-Al under conditions far from equilibrium. AIP Conf. Proc. 1698, 030004. https://doi.org/10.1063/1.4937826
Kobayashi, M., Miyagawa, M. (1987). Research and Development of Superplastic Materials. Recent Progresses and Future Prospects. ISIJ Int. 27 (9), 685-695. https://doi.org/10.2355/isijinternational1966.27.685
Kovacheva, R., Dobrev, R., Zadgorski, S., Lilova, A. (1993). Phase transformations in Zn Al Cu alloys. Mater. Charact. 31 (4), 217-224. https://doi.org/10.1016/1044-5803(93)90065-4
Lan, J., Shen, X., Liu, J., Hua, L. (2019). Strengthening mechanisms of 2A14 aluminum alloy with cold deformation prior to artificial aging. Mater. Sci. Eng. A 745, 517-535. https://doi.org/10.1016/j.msea.2018.12.051
Muñoz-Andrade, J.D., Mendoza-Allende, A., Cabrera, E., Torres-Villaseñor, G., Montemayor-Aldrete, J.A. (2007). Effect of grain size on the activation energy for plastic deformation near room temperature in a Zn-28.7 pct Al-1.9 pct Cu alloy. J. Mater. Sci. 42, 7617-7620. https://doi.org/10.1007/s10853-007-1751-2
Murphy, S. (1975). The Structure of the T′ Phase in the System AI-Cu-Zn. Metal Science 9 (1), 163-168. https://doi.org/10.1179/030634575790444414
Mykura, N., Zhu, Y.H., Murphy, S. (1986). Solid-state reactions in Zn-Al based alloys. Can. Metall. Q. 25 (2), 151-159. https://doi.org/10.1179/cmq.1986.25.2.151
Petch, N.J. (1953). The orientation relationships between cementite and α-iron. Acta Cryst. 6, 96. https://doi.org/10.1107/S0365110X53000260
Polmear, I., StJohn, D., Nie, J.F., Qian, M. (2017). Light alloys: Metallurgy of the light metals. Butterworth-Heinemann, UK. https://doi.org/10.1016/B978-0-08-099431-4.00001-4
Porter, D.A., Easterling, K.E., Sherif, M.Y. (2021). Phase transformations in metals and alloys. CRC press, USA. https://doi.org/10.1201/9781003011804
Rodríguez Jasso, A. F. (2012). Desarrollo de aleaciones de alta resistencia AI-Cu serie 2XX. Doctoral dissertation, Universidad Autónoma de Nuevo León, México. http://eprints.uanl.mx/3199/.
Shi, D., Gui, J., Tan, S.S., Wang, R. (1998). Effect of ageing in the two-phase region in a Cu-Zn-Al shape memory alloy. Mater. Sci. Eng. B 56 (1), 31-36. https://doi.org/10.1016/S0921-5107(98)00179-2
Tan, P., Qin, J., Quan, X., Yi, D., Wang, B. (2023). Co-strengthening of the multi-phase precipitation in high-strength and toughness cast Al-Cu-Zn-Mg alloy via changing Zn/Mg ratios. Mater. Sci. Eng. A 873, 145024. https://doi.org/10.1016/j.msea.2023.145024
Van Humbeeck, J., Stalmans, R., Chandrasekaran, M., Delaey, L. (1990). On the stability of shape memory alloys. In Engineering Aspects of Shape Memory Alloys. Butterworth-Heinemann, UK, pp. 96-105. https://doi.org/10.1016/B978-0-7506-1009-4.50012-3
Villegas-Cardenas, J.D., Lopez-Hirata, V.M., De Ita-De la Torre, A., Saucedo-Muñoz, M.L. (2011). Assessment of hardness in as-cast and homogenized Zn-Al-Cu alloys. Mater. Trans. 52 (8), 1581-1584. https://doi.org/10.2320/matertrans.M2011084
Villegas-Cardenas, J.D., Saucedo-Muñoz, M.L., Lopez-Hirata, V.M., Dorantes-Rosales, H.J., Gonzalez-Velazquez, J.L. (2014). Effect of phase transformations on hardness in Zn-Al-Cu Alloys. Mater. Res. 17 (5), 1137-1144. https://doi.org/10.1590/1516-1439.228913
Villegas-Cardenas, D., López-Hirata, V., Saucedo-Muñoz, M.L., Morales-Rodriguez, M., Ávila-Dávila, E.O., Radilla-Chávez, J. (2015). Optimización del costo de aleaciones Zn-Al-Cu de una dureza determinada. Dyna Spain, 90 (5), 484-490. https://doi.org/10.6036/7506
Villegas-Cardenas, J.D., López-Hirata, V., Saucedo-Muñoz, M., Camarillo Villegas, A., Morales Rodríguez, M. (2018). Evolución de la fase α en una serie de aleaciones Zn-Al-Cu de acuerdo con su tamaño y propiedades mecánicas generadas por el aumento de Cu y el proceso de envejecido. Rev. Metal. 54 (3), e126. https://doi.org/10.3989/revmetalm.126
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