Interaction of inorganic and organic compounds of physiological fluids with thermally treated Ti surfaces
DOI:
https://doi.org/10.3989/revmetalm.022Keywords:
Bovine serum albumin, Calcium phosphate, Corrosion, Foetal bovine serum, Titanium, XPSAbstract
The study of the interaction between the thermally treated Ti (TT-Ti) at 277 °C for 5 hours and the body fluids, ranging from the simplest to the most complex solution is analysed. Electrochemical techniques such as the measurement of the corrosion potential, electrochemical impedance spectroscopy and the polarization curves have been used. The characterization of TT-Ti has been performed by scanning electron microscopy, atomic force microscopy and X-ray Photoelectron Spectroscopy (XPS). The XPS reveals that the peak intensity associated with phosphate and calcium increases as immersion time does. However, the albumin covers rapidly the surface since the C peak intensity remains constant from the first day to the end of immersion time. The calcium ions have a bridging effect on the electrostatic adsorption of phosphate ions as well as that of albumin and the acidic hydroxyl groups of the oxide layer. The impedance measurement shows that the resistance of the oxide layer immersed in albumin and foetal bovine serum decrease probably due to the formation of organometallic complex. The polarization curves reveal that the presence of proteins decreases the current of anodic branch indicating that the proteins work as a barrier on the surface.
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