Optimización mediante el método de superficie de respuesta de una disolución de zinc metálico obtenido a partir de la disolución en ácido nítrico de baterías de zinc-carbono al final de su ciclo de vida

Nizamettin  Demirkıran; Merve  Şenel; Gülistan  Deniz Turhan Özdemir

doi:10.3989/revmetalm.191

Authors

Nizamettin Demirkıran Department of Chemical Engineering, Faculty of Engineering, Inonu University https://orcid.org/0000-0001-9021-2477
Merve Şenel Department of Chemical Engineering, Faculty of Engineering, Inonu University https://orcid.org/0000-0003-0738-488X
Gülistan Deniz Turhan Özdemir Department of Chemical Engineering, Faculty of Engineering, Inonu University https://orcid.org/0000-0003-4749-1989

DOI:

https://doi.org/10.3989/revmetalm.191

Keywords:

Dissolution, Nitric acid, Response surface method, Waste battery, Metallic zinc

Abstract

En este estudio, se investigaron los efectos interactivos de las variables del proceso: concentración de ácido nítrico, la cantidad de zinc disuelta en la batería y el tiempo de reacción sobre la eficiencia de la disolución de zinc metálico en soluciones de ácido nítrico aplicando la metodología de superficie de respuesta (RSM). Se encontró que la eficiencia de disolución aumentaba al aumentar la concentración de ácido nítrico y el tiempo de reacción y disminuía al hacerlo la cantidad de zinc. Se aplicó el análisis de regresión múltiple a los datos experimentales para observar los efectos interactivos de los parámetros experimentales. Se obtuvo la ecuación polinomial de segundo orden. Las condiciones experimentales óptimas se determinaron mediante el uso del módulo de optimización en el software Design-Expert, y se encontraron diferentes puntos de solución.

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