Optimization of WC-NiCrB-Al-Co coating powder composition for enhanced microhardness and reduced porosity: An I-Optimal design approach

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DOI:

https://doi.org/10.3989/revmetalm.e276.1705

Keywords:

Coating composition, Coating powder optimization, High-performance coatings, I-optimal design, Microhardness enhancement, Porosity reduction

Abstract


This study investigates the optimization of coating powder composition for enhanced microhardness and reduced porosity. Using an I-optimal design approach, the research explores the effects of varying weight percentages of Tungsten Carbide (WC), Nickel-Chrome-Boron (Ni-Cr-B), Aluminum (Al), and Cobalt (Co) on coating properties. The experimental design matrix consisted of 16 trials, including four replicated experiments. Response surface methodology and ANOVA were employed to analyze the relationship between formulation factors and responses. Results indicate that WC content positively correlates with microhardness, while Al content increases porosity. The optimal coating composition was determined to be 65% WC, 25% Ni-Cr-B, 5% Al, and 5% Co, achieving a desirability value of 0.881. This study provides insights into the complex interactions between coating components and their impact on critical properties, offering a foundation for developing high-performance coatings with enhanced resistance to oxidation, corrosion, and erosion for various industrial applications.

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References

Abu-warda, N., Bedmar, J., García-Rodríguez, S., Utrilla, M.V., Torres, B., Rams, J. (2024). Impact of molten salts composition on the corrosion behavior of NiMoCr and CoNiCrAl coatings on L-PBF 316L stainless steel for CSP plants. Surf. Coat. Technol. 482, 130744. https://doi.org/10.1016/j.surfcoat.2024.130744

Ali, Md.R., Chowdhury, M.A., Shahin, M., Rahman, Md.M., Ali, Md.O., Gafur, Md.A. (2024). Multi-physical and anti-corrosion properties of graphene-reinforced epoxy nanocomposite coatings for industrial applications. Arab. J. Chem. 17 (1), 105424. https://doi.org/10.1016/j.arabjc.2023.105424

Bogdan, M., Peter, I. (2024). A Comprehensive Understanding of Thermal Barrier Coatings (TBCs): Applications, Materials, Coating Design and Failure Mechanisms. Metals 14 (5), 575. https://doi.org/10.3390/met14050575

Bordeasu, I., Ghiban, B., Micu, L.M., Luca, A.N., Demian, A.M., Istrate, D. (2023). The Influence of Heat Aging Treatments on the Cavitation Erosion Behavior of a Type 6082 Aluminum Alloy. Materials 16 (17), 5875. https://doi.org/10.3390/ma16175875 PMid:37687570 PMCid:PMC10488434

Bursich, S., Morelli, S., Bolelli, G., Cavazzini, G., Rossi, E., Mecca, F.G., Petruzzi, S., Bemporad, E., Lusvarghi, L. (2024). The effect of ceramic YSZ powder morphology on coating performance for industrial TBCs. Surf. Coat. Technol. 476, 130270. https://doi.org/10.1016/j.surfcoat.2023.130270

Cao, Q.Z., Fan, L., Chen, H.Y., Xu, Y.R., Dong, L.H. (2022). Corrosion behavior of WC-Co coating by plasma transferred arc on EH40 steel in low-temperature. High Temp. Mater. Process. 41 (1), 191-205. https://doi.org/10.1515/htmp-2022-0010

Celik, I., Benli, B. (2024). The effect of WC-12Co and CrC-NiCr hard coatings applied by HVOF method on the microstructure, mechanical, and surface properties of steel. Metall. Res. Technol. 121 (3), 318. https://doi.org/10.1051/metal/2024034

Dai, S., Cui, M., Li, J., Zhang, M. (2024). Cold Spray Technology and Its Application in the Manufacturing of Metal Matrix Composite Materials with Carbon-Based Reinforcements. Coatings 14 (7), 822 14, 822. https://doi.org/10.3390/coatings14070822

Das, A., Das, S.R., Panda, J.P., Dey, A., Gajrani, K., Somani, N., Gupta, N.K. (2022). Machine learning-based modeling and optimization in hard turning of AISI D6 steel with advanced AlTiSiN-coated carbide inserts to predict surface roughness and other machining characteristics. Surf. Rev. Lett. 29 (10). https://doi.org/10.1142/S0218625X22501372

Du, Y., Chen, H., Li, Z., Liang, Q. (2025). Effect of WC Content on the Wear Resistance of WC/Ni60 Composite Coatings on 35CrMoV Steel by Laser Cladding. J. Mater. Eng. Perform. 1-13. https://doi.org/10.1007/s11665-025-11202-9

Gadore, V., Mishra, S.R., Singh, A.K., Ahmaruzzaman, M. (2024). Advances in boron nitride-based nanomaterials for environmental remediation and water splitting: a review. RSC Adv. 14 (5), 3447-3472. https://doi.org/10.1039/D3RA08323C PMid:38259991 PMCid:PMC10801356

Gainey, B., Gandolfo, J., Yan, Z., Vedpathak, K., Kumar, R., Jordan, E.H., Sellnau, M., Filipi, Z., Lawler, B. (2024). A two-material thermal barrier coating spatially tailored for high-efficiency GCI combustion. Int. J. Engine Res. 25 (1), 156-169. https://doi.org/10.1177/14680874231194386

Golla, C.B., Narasimha Rao, R., Ismail, S., Gupta, M. (2024). Experimental investigations with machine learning techniques for understanding of erosion wear in advanced aluminum nanocomposites. Proc. Inst. Mech. Eng., Part E. https://doi.org/10.1177/09544089241253405

Górnik, M., Jonda, E., Nowakowska, M., Łatka, L. (2021). The Effect of Spray Distance on Porosity, Surface Roughness and Microhardness of WC-10Co-4Cr Coatings Deposited by HVOF. Adv. Mater. Sci. 21 (4), 99-111. https://doi.org/10.2478/adms-2021-0028

Illana, A., de Miguel, M.T., García-Martín, G., Gonçalves, F.P., Sousa, M.G., Pérez, F.J. (2022). Experimental study on steam oxidation resistance at 600 °C of Inconel 625 coatings deposited by HVOF and laser cladding. Surf. Coat. Technol. 451, 129081. https://doi.org/10.1016/j.surfcoat.2022.129081

Indupuri, S., Kumar, R., Kumar, K.V., Kiran, P.S., Kumari, P., Kumar Keshri, A. (2025a). Tailoring the stoichiometry in NdNbO4 for advanced thermal barrier coating applications. J. Am. Ceram. Soc. 108 (2), e20199. https://doi.org/10.1111/jace.20199

Indupuri, S., Kumar, R., Sai Kiran, P., Satish, C., Keshri, A.K. (2025b). Unveiling the mechanical and thermal properties of ferroelastic Nd3NbO7-NdNbO4 composite coating for advanced TBC applications. J. Alloys Compd. 1036, 181944. https://doi.org/10.1016/j.jallcom.2025.181944

Iqbal, A., Moskal, G. (2023). Recent Development in Advance Ceramic Materials and Understanding the Mechanisms of Thermal Barrier Coatings Degradation. Arch. Computat. Methods Eng. 30, 4855-4896. https://doi.org/10.1007/s11831-023-09960-7

Keshavamurthy, R., Tambrallimath, V., Patil, S., Rajhi, A.A., Duhduh, A.A., Khan, T.M.Y. (2023). Mechanical and Wear Studies of Boron Nitride-Reinforced Polymer Composites Developed via 3D Printing Technology. Polymers 15 (22), 4368. https://doi.org/10.3390/polym15224368 PMid:38006092 PMCid:PMC10675459

Kraft, S., Peters, O., Schille, J., Mušálek, R., Martan, J., Dlouhá, Ž., Klečka, J., Matějíček, J., Houdková, Š., Moskal, D., Vilémová, M., Löschner, U. (2024). High-Speed Laser Surface Structuring for Thermal Spray Coating Preparation. Phys. Stat. Sol. A 221 (15), 2300710. https://doi.org/10.1002/pssa.202300710

Leena, S., Nanoth, R., Karingamanna, J., Sabarish Narayanan, B., Bhagavatula, S.G.K., Rajan, K.P., Gopanna, A. (2024). Investigations on morphology, tribology, rheology, thermo-mechanical properties, and EMI shielding of WC/MWCNT nanohybrids in polypropylene. J. https://doi.org/10.1177/07316844241240565

Reinf. Plast. Compos. 44 (19), 1603-1631.

Leng, K., Romero, A.R., Curry, N., Hussain, T. (2024). Multilayer GZ/YSZ thermal barrier coating from suspension and solution precursor plasma spray. Ceram. Int. 50 (1), 631-649. https://doi.org/10.1016/j.ceramint.2023.10.142

Li, C.J., Luo, X.T., Yao, S.W., Li, G.R., Li, C.X., Yang, G.J. (2022). The Bonding Formation during Thermal Spraying of Ceramic Coatings: A Review. J. Therm. Spray Technol. 31, 780-817. https://doi.org/10.1007/s11666-022-01379-z

Li, W., Wang, P., Wang, S., Duan, Z., Liu, L., Wang, Y., Xu, M. (2023). In Situ Synthesis of Graphene Oxide-Sealed LDHs Coatings: A Novel Approach to Enhancing Corrosion Resistance and Tribological Performance on Magnesium Alloys. Coatings 13 (9), 1544. https://doi.org/10.3390/coatings13091544

Lokachari, S., Leng, K., Rincon Romero, A., Curry, N., Brewster, G., Norton, A., Hussain, T. (2024). Processing-Microstructure-Properties of Columns in Thermal Barrier Coatings: A Study of Thermo-Chemico-Mechanical Durability. ACS Appl. Mater. Interfaces 16 (8), 10646- https://doi.org/10.1021/acsami.3c16681 PMid:38349273 PMCid:PMC10910460

Ma, W., Cong, Y., Gao, C., Zhang, J. (2025). Adaptive Laser Modulation Strategy for Femtosecond Laser Surface Texturing of Uniform Microcorner Features. Adv. Eng. Mater. 7 (15), 2500538. https://doi.org/10.1002/adem.202500538

Mathanbabu, M., Thirumalaikumarasamy, D., Tamilselvi, M., Kumar, S. (2022). Optimization of plasma spray process variables to attain the minimum porosity and maximum hardness of the LZ/YSZ thermal barrier coatings utilizing the response surface approach. Mater. Res. Express 9 (9), 096505. https://doi.org/10.1088/2053-1591/ac8857

Mathiyalagan, S., Rossetti, M., Björklund, S., Basu, S., Balila, N.J., Sowers, S., Joshi, S. (2024). Deposition characteristics and tribological performance of atmospheric plasma sprayed diamond metal matrix composite (DMMC) coatings. Mater. Chem. Phys. 315, 128920. https://doi.org/10.1016/j.matchemphys.2024.128920

Mohankumar, A., Duraisamy, T., Sampathkumar, D., Ranganathan, S., Balachandran, G., Kaliyamoorthy, M., Mariappan, M., Mulugeta, L. (2022). Optimization of Cold Spray Process Inputs to Minimize Porosity and Maximize Hardness of Metal Matrix Composite Coatings on AZ31B Magnesium Alloy. J. Nanomater. 2022, 900150. https://doi.org/10.1155/2022/7900150

Park, J.S., Bang, H.R., Bin Yun, D., Jamadar, A.S., Pedanekar, R.S., Lee, S.C., Choi, J.K., Kim, S.J. (2025). Superior performance of 18Mn3Cr0.5Mo1V ferrous alloy for strength, ductility, and prolonged corrosion resistance in seawater. Npj Mater. Degrad. 9, 18. https://doi.org/10.1038/s41529-025-00564-z

Rakhadilov, B., Maulet, M., Abilev, M., Sagdoldina, Z., Kozhanova, R. (2021). Structure and Tribological Properties of Ni-Cr-Al-Based Gradient Coating Prepared by Detonation Spraying. Coatings 11 (12), 218. https://doi.org/10.3390/coatings11020218

Shahbazi, H., Vakilifard, H., Nair, R.B., Liberati, A.C., Lima, R.S., Stoyanov, P., Moreau, C. (2024). High Entropy Alloy Bond Coats for Thermal Barrier Coatings: A Review. J. Therm. Spray Technol. 33, 430-446. https://doi.org/10.1007/s11666-023-01701-3

Siripongsakul, T., Kettrakul, P., Kanjanaprayut, N., Promdirek, P. (2024). Effect of Si Addition in NiCrAl Coating on Corrosion in Molten Nitrate Salt. Metals 14 (8), 902. https://doi.org/10.3390/met14080902

Somani, N., Walia, A.S., Gupta, N.K., Panda, J.P., Das, A., Das, S.R. (2023). Data driven surrogate model-based optimization of the process parameters in electric discharge machining of D2 steel using Cu-SiC composite tool for the machined surface roughness and the tool wear. https://doi.org/10.3989/revmetalm.242

Rev. Metal. 59 (2), e242.

Srinivas, V., Pathem, U., Venkataramana, V.S.N., Chebattina, K.R.R. (2019). Mechanical, Anticorrosion, and Tribological Properties of Nanostructured WC-Co/Cr3C2-NiCr Multilayered Graded Coating on Aluminum Substrate. Metall. Mater. Trans. A 50, 1985-1994. https://doi.org/10.1007/s11661-019-05117-z

Sundaram, S., Singaravelu, C., Malaiperumal, V. (2024). Hot Corrosion Study of Plasma-Sprayed Optimized WC-NiCrB-Al-Co Coating Mixture on Stainless Steels for Boiler Environment. J. Mater. Eng. Perform. 34, 10697-10718. https://doi.org/10.1007/s11665-024-09877-7

Tillmann, W., Khalil, O., Abdulgader, M. (2019). Porosity Characterization and Its Effect on Thermal Properties of APS-Sprayed Alumina Coatings. Coatings 9 (10), 601. https://doi.org/10.3390/coatings9100601

Vakilifard, H., Shahbazi, H., Liberati, A.C., Saraswathy, R.B.N., Lima, R.S., Pugh, M.D., Moreau, C. (2024). High Entropy Oxides as Promising Materials for Thermal Barrier Topcoats: A Review. J. Therm. Spray Technol. 33, 447-470. https://doi.org/10.1007/s11666-024-01744-0

Veeresh, K.C., Banker, K., Sharmila, L., Manohara, M., Prasad, V.V., Jaiganesh, V., Rajendiran, M., Prasad, A.R. (2025). Erosion Resistance Evaluation of WC and NiCr Coatings on SS316 Steel in Hydro Machinery Applications: An HVOF Spraying Approach. AIP Conf. Proc. 3270, 020261. https://doi.org/10.1063/5.0263876

Vidakis, N., Moutsopoulou, A., Petousis, M., Michailidis, N., Charou, C., Mountakis, N., Argyros, A., Papadakis, V., Dimitriou, E. (2023). Medical-Grade PLA Nanocomposites with Optimized Tungsten Carbide Nanofiller Content in MEX Additive Manufacturing: A Rheological, https://doi.org/10.3390/polym15193883 PMid:37835932 PMCid:PMC10575008

Morphological, and Thermomechanical Evaluation. Polymers 15 (19), 3883.

Wood, J., Morscher, G., Panakarajupally, R., Shi, J., Li, W. (2025). High Temperature Creep and Elastic Properties of Environmental Barrier Coatings. Proceedings of the ASME Turbo Expo 1. https://doi.org/10.1115/GT2025-153375

Xie, H., Champagne, V.K., Zhong, W., Clifford, B., Liu, S., Hu, L., Zhao, J.C., Clarke, D.R. (2024). Design, Fabrication, and Screening of Environmental-Thermal Barrier Coatings Prepared by Ultrafast High-Temperature Sintering. Adv. Funct. Mater. 34 (10), 2309978. https://doi.org/10.1002/adfm.202309978

Yalçınyüz, B.A., Kamutzki, F., Gurlo, A., Rupprecht, C. (2023). Optimization of Segmented Thermal Barrier Coatings (s-TBCs) for High-Temperature Applications. J. Therm. Spray Technol. 32, 2636-2646. https://doi.org/10.1007/s11666-023-01649-4

Yang, C., Chen, P., Wu, W., Sheng, L., Zheng, Y., Chu, P.K. (2024). A Review of Corrosion-Resistant PEO Coating on Mg Alloy. Coatings 14 (4), 451. https://doi.org/10.3390/coatings14040451

Yang, X., Huang, Z., Liao, X., Lei, H., Hao, D., Zhang, T., Jiang, B. (2025). The Effect of Oxidation Time on the Organization and Corrosion Performance of 6061 Aluminum Alloy Micro-Arc Oxidation Coatings. Coatings 15 (2), 117. https://doi.org/10.3390/coatings15020117

Yimyai, T., Crespy, D., Rohwerder, M. (2023). Corrosion-Responsive Self-Healing Coatings. Adv. Mater. 35 (47), e2300101. https://doi.org/10.1002/adma.202300101 PMid:36939547

Yu, J., Liu, X., Yu, Y., Li, Z., Xu, S., Li, H., Liu, P., Wang, L. (2022). Effect of HVOF Spraying Process on Particle Behavior of Fe-Based Amorphous Alloy Coatings. .J Therm. Spray Technol. 31, 2448-2462. https://doi.org/10.1007/s11666-022-01476-z

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Published

2025-12-15

How to Cite

Sundaram, S., Singaravelu, C., & Malaiperumal, V. (2025). Optimization of WC-NiCrB-Al-Co coating powder composition for enhanced microhardness and reduced porosity: An I-Optimal design approach. Revista De Metalurgia, 61(1), e276. https://doi.org/10.3989/revmetalm.e276.1705

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