Uses of the potassium permanganate to eliminate copper cyanide from waste water resulting from a lixiviation plant in a gold mine (I)
DOI:
https://doi.org/10.3989/revmetalm.0846Keywords:
Cyanide, Hydrometallurgy, Gold, Potassium permanganate, Copper cyanideAbstract
The use of cyanide in the hydrometallurgical and chemical industries has led to the emergence of a major environmental problem due to its high toxicity. The wastewater generated at these plants is hazardous to the environment and therefore must be managed properly. For this purpose, they undergo detoxification processes after lodes from the plant are accumulated in waste-resistant containment ponds that mast be waterproof to prevent environmental disasters from leakages or massive flood. This work shows the results obtained in laboratory tests carried out with plant waters and demonstrates the efficacy of potassium permanganate as an oxidant of cyanide wastewater from a gold hydrometallurgical plant. In the process the destruction of the copper cyanide complexes in solution is achieved and copper metal ions are eliminated through precipitation mostly as hydroxide.
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References
[1] F. Habashi, C.I.M. Bulletin 80 (1987) 108-114.
[2] P. Navarro, C. Vargas, R. Alvarez y F.J. Alguacil, Rev. Metal. Madrid 41 (2005) 12-20.
[3] P. Navarro, C. Vargas, F.J. Alguacil y R. Alvarez, Rev. Metal. Madrid Vol. Extr. (2005) 69-73.
[4] J.J. Yáñez-Traslaviña, M.A. Vargas-Avila, I.H. García-Páez y J.E. Pedraza-Rosas, Rev. Metal. Madrid 41 (2005) 116-125.
[5] L. Chacón, F. Ruiz y R. Zapico, Rev. Metal. Madrid Vol. Extr. (2005) 390-394.
[6] F. Nava-Alonso, E. Elorza-Rodríguez, A. Uribe-Salas y R. Pérez-Garibay, Rev. Metal. Madrid 43(2007) 20-28.
[7] J.S. Scott y J. Ingles, Canadian Mineral Processors Thirteenth Annual Meeting, Otawa, Canadá, The Canadian Mineral Processors Society (Eds.), Otawa, Canadá, 1981, pp. 380-418.
[8] J.D. Desai, C. Ramakrishna, P.S. Patel y S.K. Awasthi, Chemical Engineering World XXXIII (6), EXICOM, India Pvt Ltd (Eds.), Mumbai, India (1998) pp. 115-121.
[9] Diario Oficial de las Comunidades Europeas, L 330, 5/12/1998, Directiva 98/83/Ce del Consejo, 3/11/1998.
[10] B. Fernández, Tesis Doctoral, Universidad de Oviedo, 2007
[11] R.R. Dash, A. Gaur y Ch. Balomajumder. J. Harzard. Mater. 163 (2009) 1-11. doi:10.1016/j.jhazmat.2008.06.051 PMid:18657360
[12] R.R. Dash, Ch. Balomajumder y A. Kumar. J. Harzard. Mater. 152 (2008) 387-396. doi:10.1016/j.jhazmat.2007.07.009 PMid:17706348
[13] T.I. Mudder y M. Botz, Eur. J. Miner. Process. Environ. Prot. 4 (2004) 100-110.
[14] J.P. Sancho, B. Fernandez y F. Bellón, Int. Mine Water Cong., J. Loredo & F. Pendás (Eds.), Oviedo, España, 2005, pp. 413-417.
[15] A. Akcil, Biotechnol. Adv. 21 (2003) 501-511. doi:10.1016/S0734-9750(03)00099-5
[16] A. Ballester, J. Sancho y L. F. Verdeja, Metalurgia Extractiva. Fundamentos, Ed. Síntesis, S.A., 2000, pp. 1-512.
[17] A.G. Sharpe, Academic Press, (Eds.), New York, EE. UU., 1976, pp. 1-300.
[18] J.H. Baxendale and D.T. Westcott, J. Chem. Soc. (1959) 2.347-2.351.
[19] G. Handbuch, Cu [B] 60, Verlag Chemie, Ed., Frankfurt, Alemania, 1965. 1-1.147.
[20] T. Tran, K. Fernando, K Lee y F. Lucien, Annual Meeting of TMS, The Mineral Metals & Materials Society, Ed., New Orleans, Louisiana, EE. UU., 2001, pp. 289-302.
[21] G.C. Lukey, J.S.J. Van Deventer, S.T. Huntington, R.L. Chowdhury y D.C. Shallcross, Hydrometallurgy 53 (1999) 233-244. doi:10.1016/S0304-386X(99)00047-X
[22] T. Xue, V.S.T. Ciminelli y K.Osseo-Asare, Precious Metals Mining, Extraction and Processing, AIME (Eds.), Warrendale, PA, New York, EE. UU., 1984, pp. 283-297.
[23] Carus Chemical Company. Cairox
[24] P. Vella, Sixth Int. Symp. Chemical Oxidation, Technomic (Eds.), Vanderbilt University, Nasville, Tennesse, EE. UU., 1996, pp. 28-30.
[25] K.L. Rees y J.S.J. Van Deventer, Miner. Eng.12 (1999) 877-892. doi:10.1016/S0892-6875(99)00075-8
[26] M. Pourbaix, Atlas D’equilibres Ë lectrochimiques, Ed. Gauthier-Villars, París, Francia, 1963, pp. 1-644.
[27] T.I. Mudder, The Cyanide Monograph Mining Journal Books, The Mining Journal Ltd., Ed., Londres, Inglaterra, 1988, pp. 329-353.
[28] J. Marsden y I. House, The Chemistry of Gold Extraction, Ellis Horwood, Ed., Chichester, Inglaterra, 1992, pp. 309-378.
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