Extracto acuoso natural de <em>Morinda Citrifolia</em> como inhibidor de corrosión del acero AISI-1045 en ambientes ácidos de HCl

Mara Franco; Héctor Herrera-Hernández; Iván García-Orozco; Pilar Herrasti

doi:10.3989/revmetalm.128

Authors

Mara Franco Laboratorio de investigación y Desarrollo de Materiales Avanzados (LIDMA), Facultad de Química, Universidad Autónoma del Estado de México https://orcid.org/0000-0003-1793-462X
Héctor Herrera-Hernández Universidad Autónoma del Estado de México, IIN-Laboratorio de Electroquímica y Corrosión de Materiales Industriales https://orcid.org/0000-0002-1485-3624
Iván García-Orozco Laboratorio de investigación y Desarrollo de Materiales Avanzados (LIDMA), Facultad de Química, Universidad Autónoma del Estado de México https://orcid.org/0000-0003-1793-462X
Pilar Herrasti Universidad Autónoma de Madrid, Facultad de Ciencias, Dpto. de Química Física https://orcid.org/0000-0003-1067-0780

DOI:

https://doi.org/10.3989/revmetalm.128

Keywords:

Adsorption, AISI 1045, Corrosion, Extract, Inhibitor, Morinda Citrifolia

Abstract

Both the organic and inorganic compounds commonly used in the industry to inhibit the corrosion process of metals and its alloys are mostly composed by highly toxic chemicals, in addition to being more expensive. In this research sugar-components derived from the Morinda Citrifolia (MC) leaves have been extracted in aqueous solution to perform a natural inhibitor capable to control de corrosion damage, which can replace the traditional inhibitors, being environmentally friendly. The experimental results indicate that this compound has shown excellent performance as corrosion inhibitor, reaching inhibition efficiency (EI), values up to 90% at inhibitor concentrations ranging 0.8 to 2 g·L^-1 and immersion times of about 1 to 4 h. It has been found that the inhibition process takes place by the adsorption of the molecules on the surface of the metal (AISI 1045), by a physisorption mechanism.

Downloads

Download data is not yet available.

References

Abdallah, M., Kamar, E.M., Salah Eid, El-Etre, A.Y. (2016). Animal glue as green inhibitor for corrosion of aluminum and aluminum-silicon alloys in sodium hydroxide solutions. J. Mol. Liq. 220, 755–761. https://doi.org/10.1016/j.molliq.2016.04.062

Abiola, O.K., James, A.O. (2010). The effects of Aloe Vera extract on corrosion and kinetics of corrosion process of zinc in HCl solution. Corros. Sci. 52 (2), 661–664. https://doi.org/10.1016/j.corsci.2009.10.026

ASTM G1-90 (1990). Standard Practice for Preparing, Cleaning, and Evaluation Corrosion test Specimens. ASTM standards.

Bahrami, M.J., Hosseini, S.M.A., Pilvar, P. (2010). Experimental and theoretical investigation of organic compounds as inhibitors for mild steel corrosion in sulfuric acid medium. Corros. Sci. 52 (9), 2793–2803. https://doi.org/10.1016/j.corsci.2010.04.024

De Souza, F.S., Spinelli, A. (2009). Caffeic Acid as a Green Corrosion Inhibitor for Mild Steel. Corros. Sci. 51 (3), 642–649. https://doi.org/10.1016/j.corsci.2008.12.013

Deng, S., West, B.J., Jensen, C.J. (2008). Simultaneous characterisation and quantitation of flavonol glycosides and aglycones in noni leaves using a validated HPLC-UV/MS method. Food Chem. 111 (2), 526–529. https://doi.org/10.1016/j.foodchem.2008.04.021 PMid:26047461

Deng, S., Li, X. (2012). Inhibition by Ginkgo leaves extract of the corrosion of steel in HCl and H2SO4 solutions. Corros. Sci. 55, 407–415. https://doi.org/10.1016/j.corsci.2011.11.005

Herrera-Hernández, H., Franco-Tronco, M.I., Miranda-Hernández, J.G., Hernández-Sánchez, E., Espinoza- Vázquez, A., Fajardo, G. (2015). Gel de Aloe-Vera como potencial inhibidor de la corrosión del acero de refuerzo estructural. Avances en Ciencias e Ingeniería 6 (3), 9–23.

Hooshmand Zaferani, S., Majid S., Zaarei, D., Reza Shishesaz, M. (2013). Application of eco-friendly products as corrosion inhibitors for metals in acid pickling processes - A Review. J. Environ. Chem. Eng. 1 (4), 652–657. https://doi.org/10.1016/j.jece.2013.09.019

Ji, G., Kumar Shukla, S., Dwivedi, P., Sundaram, S., Prakash, R. (2011). Inhibitive Effect of Argemone Mexicana Plant Extract on Acid Corrosion of Mild Steel. Ind. Eng. Chem. Res. 50 (21), 11954–11959. https://doi.org/10.1021/ie201450d

Kesavan, D., Gopiraman, M., Sulochana, N. (2012). Green Inhibitors for Corrosion of Metals: A Review. Chem. Sci. Rev. Lett. 1 (1), 1–8.

Krishnaveni, K., Ravichandran, J. (2014). Effect of Aqueous Extract of Leaves of Morinda Tinctoria on Corrosion Inhibition of Aluminium Surface in HCl Medium. T. Nonferr. Metal Soc. China 24 (8). 2704–2712. https://doi.org/10.1016/S1003-6326(14)63401-4

Lozano, I., Mazario, E., Olivares-Xometl, C.O., Likhanova, N.V., Herrasti, P. (2014). Corrosion Behaviour of API 5LX52 Steel in HCl and H2SO4 Media in the Presence of 1,3-Dibencilimidazolio Acetate and 1,3-Dibencilimidazolio Dodecanoate Ionic Liquids as Inhibitors. Mater. Chem. Phys. 147 (1–2), 191–197. https://doi.org/10.1016/j.matchemphys.2014.04.029

Mandujano-Ruíz, A., Mortales-Hernández, J., Herrera-Hernández, H., Corona-Almazán, L.E., Juárez García, J.M. (2017). Evaluación del comportamiento electroquímico del extracto de nopal (Opuntia Ficus-Indica) como posible inhibidor de la corrosión. Rev. Metal. 53 (4), e108. https://doi.org/10.3989/revmetalm.108

Mourya, P., Banerjee, S., Singh, M.M. (2014). Corrosion Inhibition of Mild Steel in Acidic Solution by Tagetes Erecta (Marigold Flower) Extract as a Green Inhibitor. Corros. Sci. 85, 352–363. https://doi.org/10.1016/j.corsci.2014.04.036

Müller, J.C., Botelho, G.G., Bufalo, A.C., Boareto, A.C., Rattmann, Y.D., Martins, E.S., Cabrini, D.A., Outki, M.F., Dalsenter, P.R. (2009). Morinda Citrifolia Linn (Noni): In Vivo and in Vitro Reproductive Toxicology. J. Ethnopharmacol. 121 (2), 229–233. https://doi.org/10.1016/j.jep.2008.10.019 PMid:19015020

Prabakaran, M., Seung-Hyun, K., Kalaiselvi, K., Hemapriya, V., Chung, III-M. (2016a). Highly Efficient Ligularia Fischeri Green Extract for the Protection against Corrosion of Mild Steel in Acidic Medium: Electrochemical and Spectroscopic Investigations. J. Taiwan Inst. Chem. E. 59, 553–562. https://doi.org/10.1016/j.jtice.2015.08.023

Prabakaran, M., Kim, S.-H., Hemapriya, V., Gopiraman, M., Kim, I.S., Chung, III-M. (2016b). Rhus Verniciflua as a Green Corrosion Inhibitor for Mild Steel in 1 M H2SO4. RSC Adv. 6 (62), 57144–57153. https://doi.org/10.1039/C6RA09637A

Prabakaran, M., Kim, S.-H., Mugila, N., Hemapriya, V., Parameswari, K., Chitra, S., Chung, III-M. (2017). Aster Koraiensis as Nontoxic Corrosion Inhibitor for Mild Steel in Sulfuric Acid. J. Ind. Eng. Chem. 52, 235–242. https://doi.org/10.1016/j.jiec.2017.03.052

Raja, P.B., Qureshi, A.K., Rahim, A.A., Osman, H., Awang, K. (2013). Neolamarckia cadamba alkaloids as eco-friendly corrosion inhibitors for mild steel in 1M HCl media. Corros. Sci. 69, 292–301. https://doi.org/10.1016/j.corsci.2012.11.042

Sang, S., Cheng, X., Zhu, N., Stark, R.E., Badmaev, V., Ghai, G., Rosent, R.T., Ho, C.T. (2001). Flavonol glycosides and novel iridoid glycoside from the leaves of Morinda citrifolia. J. Agr. Food Chem. 49 (9), 4478–4481. https://doi.org/10.1021/jf010492e

Satapathy, A.K., Gunasekaran, G., Sahoo, S.C., Amit, K., Rodrigues, P.V. (2009). Corrosion inhibition by Justicia Gendarussa plant extract in hydrochloric acid solution. Corros. Sci. 51 (12), 2848–2856. https://doi.org/10.1016/j.corsci.2009.08.016

Torres, V.V., Magalhães, M., Viana, G.M., Aguilar, S.P., Machado, S.P., Orofino, H., D'Elia, E. (2014). Study of Thioureas Derivatives Synthesized from a Green Route as Corrosion Inhibitors for Mild Steel in HCl Solution. Corros. Sci. 79, 108–118. https://doi.org/10.1016/j.corsci.2013.10.032

Verma, Ch., Ebenso, E.E. Quraishi, M.A. (2017). Ionic Liquids as Green and Sustainable Corrosion Inhibitors for Metals and Alloys: An Overview. J. Mol. Liq. 233, 403–414. https://doi.org/10.1016/j.molliq.2017.02.111

Wang, J., Qin, X., Chen, Z., Ju, Z., He, W., Tan Y., Zhou, Z., Tu, Z; Lu, F., Liu, Y. (2016). Two new anthraquinones with antiviral activities from the barks of Morinda citrifolia (Noni). Phytochem. Lett. 15, 13–15. https://doi.org/10.1016/j.phytol.2015.11.006

Zin, Z.M., Abdul-Hamid, A., Osman, A. (2002). Antioxidative activity of extracts from Mengkudu (Morinda Citrifolia L.) root, fruit and leaf. Food Chem. 78 (2), 227–231. https://doi.org/10.1016/S0308-8146(01)00402-2