Propiedades mecánicas y eléctricas de las aleaciones ternarias de Ag-Ge-In

Aleksandar Marković; Duško Minić; Milena Premović; Dragan Manasijević

doi:10.3989/revmetalm.161

Authors

Aleksandar Marković University of Priština, Faculty of Technical Science https://orcid.org/0000-0002-1221-4351
Duško Minić University of Priština, Faculty of Technical Science https://orcid.org/0000-0002-0432-6038
Milena Premović University of Priština, Faculty of Technical Science https://orcid.org/0000-0003-0532-7048
Dragan Manasijević University of Belgrade, Technical Faculty in Bor https://orcid.org/0000-0002-7828-8994

DOI:

https://doi.org/10.3989/revmetalm.161

Keywords:

Hardness properties, Electrical properties, Microstructures, Ternary alloys of the Ag-Ge-In system

Abstract

Mechanical (Brinell hardness test) and electrical properties of some selected ternary Ag-Ge-In alloys have been investigated in this study. By using obtained results for properties and ANOVA analysis it is suggested mathematical model for calculation properties for every composition of alloys. Microstructures of alloys have been carried out by using optical microscopy and scanning electron microscopy (SEM). Phases presented in microstructures have been detected by x-ray diffraction (XRD) analysis and compositions by energy dispersive spectrometry (EDS). Experimentally determined results are compared with calculated data. Calculation of isothermal section at 25 °C was carried out by using optimized thermodynamic parameters for the constitutive binary systems. Good overall agreement between experimental and calculated values was obtained.

Downloads

Download data is not yet available.

References

Campbell, A.N., Wagemann, R., Ferguson, R.B. (1970). The silver-indium system: thermal analysis, photomicrography, electron microprobe, and X-ray powder diffraction results. Can. J. Chem. 48 (11), 1703-1715. https://doi.org/10.1139/v70-281

Chen, Y.C., Rettner, C.T., Raoux, S., Burr, G.W., Chen, S.H., Shelby, R.M., Salinga, M., Risk, W., Happ, T.D., McClelland, G.M., Breitwisch, M., Schrott, A., Philipp, J.B., Lee, M.H., Cheek, R., Nirschl, T., Lamorey, M., Chen, C.F., Joseph, E., Zaidi, S., Yee, B., Lung, H.L., Bergmann, R., Lam, C. (2006). Ultra-Thin Phase-Change Bridge Memory Device Using GeSb. IEEE Int. Electron Dev. Mtg . 777 , San Francisco, CA . https://doi.org/10.1109/IEDM.2006.346910

Cooper, A.S. (1962). Precise lattice constants of germanium, aluminum, gallium arsenide, uranium, sulphur, quartz and sapphire. Acta Crystallogr. 15, 578-582. https://doi.org/10.1107/S0365110X62001474

Cornell, J.A. (2002). Experiments with Mixtures: Designs, Models, and the Analysis of Mixture Data. 3rd Ed., John Wiley & Sons, Inc, New York. https://doi.org/10.1002/9781118204221

Chevalier P.Y. (1989). A thermodynamic evaluation of the Ge-In, Ge-Pb, Ge-Sb, Ge-Tl and Ge-Zn systems. Thermochim. Acta 155, 227-240. https://doi.org/10.1016/0040-6031(89)87148-5

Havinga, E.E., Damsma, H., Hokkeling, P. (1972). Compounds and pseudo-binary alloys with the CuAl2(C16)-type structure I. Preparation and X-ray results. J. Less Common. Met. 27 (2), 169-186. https://doi.org/10.1016/0022-5088(72)90028-8

Ielmini, D., Lacaita, A.L. (2011). Phase change materials in non-volatile storage. Mater. Today 14 (12), 600-607. https://doi.org/10.1016/S1369-7021(11)70301-7

Jette, E., Foote, F. (1935). Precision Determination of Lattice Constants. J. Chem. Phys. 3 (10), 605-609. https://doi.org/10.1063/1.1749562

Kolarević, M., Vukićević, M., Radičević, B., Bjelić, M., Grković, V. (2011). A methodology for forming the regression model of ternary system. The Seventh Triennial International Conference, Heavy Machinery, Vrnjačka Banja, pp. 1-6.

Kroupa, A., Dinsdale, A.T., Watson, A., Vrestal, J., Vızdal, J., Zemanova, A. (2007). The development of the COST 531 lead-free solders thermodynamic database. JOM 59, 20-25. https://doi.org/10.1007/s11837-007-0084-6

Lacaita, A.L., Wouters, D.J. (2008). Phase-change memories. Phys. Status Solidi A 205 (10), 2281-2297. https://doi.org/10.1002/pssa.200723561

Lazić Ž.R. (2004). Design of Experiments in Chemical Engineering: A Practical Guide. Wiley-VCH Verlag GmbH & Co. KGaA, Weiheim. https://doi.org/10.1002/3527604162 PMCid:PMC522350

Milisavljević, D., Minić, D., Premović, M., Manasijević, D., Košanin, N. (2018). Experimental examination and thermodynamic description of the ternary Ag-Ge-In system. Thermochim. Acta 665, 1-10. https://doi.org/10.1016/j.tca.2018.05.003

Nemec, P., Nazabal, V., Moreac, A., Gutwirth, J., Benes, L., Frumar, M. (2012). Amorphous and crystallized Ge-Sb-Te thin films deposited by pulsed laser: Local structure using Raman scattering spectroscopy. Mater. Chem. Phys. 136, 935-941. https://doi.org/10.1016/j.matchemphys.2012.08.024

Ou, S.L., Cheng, C.P., Yeh, C.Y., Chung, C.J., Kao, K.S., Lin, R.C. (2011). Characteristics of In-Ge-Sb-Sn-Te Thin Film Used for Phase Change Optical Recording Media. Adv. Mat. Res. 189-193, 4430-4433. https://doi.org/10.4028/www.scientific.net/AMR.189-193.4430

Premović, M., Minić, D., Cosović, V., Manasijević, D., Živković, D. (2014). Experimental Investigation and Thermodynamic Calculations of the Bi-Ge-Sb Phase Diagram. Metal. Mater. Trans. A 45, 4829-4841. https://doi.org/10.1007/s11661-014-2445-4

Premović, M., Minić, D., Mitrovica, K., Manasijević, I., Živković, D. (2015). Electrical conductivity and hardness of ternary Ge-In-Sb allyos and calculation of the isothermal section at 300 °C. Mater. Test. 57 (10), 883-888. https://doi.org/10.3139/120.110790

Premović, M., Manasijević, D., Minić, D., Živković, D. (2016). Study of electrical conductivity and hardness of ternary Ag-Ge-Sb system alloys and isothermal section calculation at 300 °C. Kovové Mater. 54 (1), 45-53. https://doi.org/10.4149/km_2016_1_45

Premović, M., Minić, D., Kolarevic, M., Manasijevic, D., Živković, D., Djordjevic, A., Milisavljevic, D. (2017a). Electrical properties of ternary Bi-Ge-Sb and Al-Cu-Sb alloys. Rev Metal. 53 (3), e098. https://doi.org/10.3989/revmetalm.098

Premović, M., Du, Y., Minic, D., Zhang, C., Manasijevic, D., Balanovic, L., Markovic, I. (2017b). Experimental investigation and thermodynamic calculation of the Cu-Ge-Sb system. J. Alloys Compd. 726, 820-832. https://doi.org/10.1016/j.jallcom.2017.08.051

Raoux, S., Wuttig, M. (2009). Phase Change Materials: Science and Application. Springer, New York. https://doi.org/10.1007/978-0-387-84874-7 PMCid:PMC2700143

Ridley, N. (1965). Densities of some indium solid solutions. J. Less Common. Met. 8 (5), 354-357. https://doi.org/10.1016/0022-5088(65)90071-8

Wang, J., Liu, Y.J., Tang, C.Y., Liu, L.B., Zhou, H.Y., Jin, Z.P. (2011). Thermodynamic description of the Au-Ag-Ge ternary system. Thermochim. Acta 512 (1-2), 240-246. https://doi.org/10.1016/j.tca.2010.11.003