La eliminación de metales tóxicos presentes en efluentes líquidos mediante resinas de cambio iónico. Parte XVI: Iron(III)/H+/Lewatit TP208

Francisco José  Alguacil

doi:10.3989/revmetalm.203

Autores/as

Francisco José Alguacil Centro Nacional de Investigaciones Metalúrgicas (CENIM-CSIC) https://orcid.org/0000-0002-0247-3384

DOI:

https://doi.org/10.3989/revmetalm.203

Palabras clave:

Efluentes líquidos, Eliminación, Hierro(III), Lewatit TP208, Nanotubos de carbono de pared múltiple

Resumen

Se ha empleado la resina de cambio iónico Lewatit TP208 en la eliminación de Fe(III) de disoluciones acuosas bajo distintas condiciones experimentales: velocidad de agitación aplicada al sistema, pH del medio acuoso y dosificación de la resina, temperatura y concentración de hierro(III) en la disolución acuosa. Se obtiene un máximo en la carga de hierro(III) en la resina empleando una velocidad de agitación de 900 min^-1, siendo este proceso de carga del metal dependiente del valor del pH dela disolución acuosa y de la dosificación de la resina. El aumento de la temperatura da lugar a una disminución de la carga de hierro(III) en la resina, resultando en un proceso endotérmico. La eliminación de Fe(III) de la disolución acuosa también depende da la concentración inicial de este elemento en la misma. Se ha investigado el proceso de carga de Fe(III) en la resina en presencia (disoluciones binarias) de otros elementos metálicos en la disolución: Cu(II), Zn(II), Cr(III), In(III), y también se ha comparado con la carga de Fe(II) en la resina Lewatit TP208. Asimismo, se compara el uso de la resina con el empleo de nanotubos de carbono de pared múltiple en la eliminación de Fe(III) de la disolución acuosa. El hierro(III) cargado en la resina se puede eluir empleando disoluciones ácidas.

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